Synthesis and kinetic regularities of the thermal decomposition of new hydrotrioxides of cyclic alcohols

Resumo

Cyclic hydrotrioxides were synthesized by low-temperature (−78 °C) ozonolysis of a series of cyclic alcohols and identified using ¹H NMR spectra. The kinetic regularities of the thermal decomposition of the synthesized hydrotrioxides were studied. The experimental proof of the induced decomposition of alcohol hydrotrioxides was obtained for the first time using cyclohexanol hydrotrioxide as an example. The influence of cyclic substituents on the thermal stability of the hydrotrioxides is shown.