Отправить статью по E-mail Synthesis and kinetic regularities of the thermal decomposition of new hydrotrioxides of cyclic alcohols
- Авторы: Grabovskiy S.A.1, Khalitova L.R.1, Fedorova A.V.2, Lobov A.N.1, Rol’nik L.Z.2, Kabal’nova N.N.1
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Учреждения:
- Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences
- Ufa State Oil Technical University
- Выпуск: Том 65, № 2 (2016)
- Страницы: 464-468
- Раздел: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/237151
- DOI: https://doi.org/10.1007/s11172-016-1322-2
- ID: 237151
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Аннотация
Cyclic hydrotrioxides were synthesized by low-temperature (−78 °C) ozonolysis of a series of cyclic alcohols and identified using 1H NMR spectra. The kinetic regularities of the thermal decomposition of the synthesized hydrotrioxides were studied. The experimental proof of the induced decomposition of alcohol hydrotrioxides was obtained for the first time using cyclohexanol hydrotrioxide as an example. The influence of cyclic substituents on the thermal stability of the hydrotrioxides is shown.
Об авторах
S. Grabovskiy
Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences
Автор, ответственный за переписку.
Email: stas_g@anrb.ru
Россия, 71 prosp. Oktyabrya, Ufa, 450054
L. Khalitova
Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences
Email: stas_g@anrb.ru
Россия, 71 prosp. Oktyabrya, Ufa, 450054
A. Fedorova
Ufa State Oil Technical University
Email: stas_g@anrb.ru
Россия, 1 ul. Kosmonavtov, Ufa, 450062
A. Lobov
Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences
Email: stas_g@anrb.ru
Россия, 71 prosp. Oktyabrya, Ufa, 450054
L. Rol’nik
Ufa State Oil Technical University
Email: stas_g@anrb.ru
Россия, 1 ul. Kosmonavtov, Ufa, 450062
N. Kabal’nova
Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences
Email: stas_g@anrb.ru
Россия, 71 prosp. Oktyabrya, Ufa, 450054
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