Synthesis and kinetic regularities of the thermal decomposition of new hydrotrioxides of cyclic alcohols
- Authors: Grabovskiy S.A.1, Khalitova L.R.1, Fedorova A.V.2, Lobov A.N.1, Rol’nik L.Z.2, Kabal’nova N.N.1
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Affiliations:
- Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences
- Ufa State Oil Technical University
- Issue: Vol 65, No 2 (2016)
- Pages: 464-468
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/237151
- DOI: https://doi.org/10.1007/s11172-016-1322-2
- ID: 237151
Cite item
Abstract
Cyclic hydrotrioxides were synthesized by low-temperature (−78 °C) ozonolysis of a series of cyclic alcohols and identified using 1H NMR spectra. The kinetic regularities of the thermal decomposition of the synthesized hydrotrioxides were studied. The experimental proof of the induced decomposition of alcohol hydrotrioxides was obtained for the first time using cyclohexanol hydrotrioxide as an example. The influence of cyclic substituents on the thermal stability of the hydrotrioxides is shown.
About the authors
S. A. Grabovskiy
Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences
Author for correspondence.
Email: stas_g@anrb.ru
Russian Federation, 71 prosp. Oktyabrya, Ufa, 450054
L. R. Khalitova
Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences
Email: stas_g@anrb.ru
Russian Federation, 71 prosp. Oktyabrya, Ufa, 450054
A. V. Fedorova
Ufa State Oil Technical University
Email: stas_g@anrb.ru
Russian Federation, 1 ul. Kosmonavtov, Ufa, 450062
A. N. Lobov
Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences
Email: stas_g@anrb.ru
Russian Federation, 71 prosp. Oktyabrya, Ufa, 450054
L. Z. Rol’nik
Ufa State Oil Technical University
Email: stas_g@anrb.ru
Russian Federation, 1 ul. Kosmonavtov, Ufa, 450062
N. N. Kabal’nova
Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences
Email: stas_g@anrb.ru
Russian Federation, 71 prosp. Oktyabrya, Ufa, 450054