Condensation products of Betti base and pyridinecarboxaldehydes


Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

Previously unknown condensation products were obtained by the reaction of the racemic Betti base with 2-, 3- and 4-pyridinecarboxaldehydes. It was established that they have a naphthoxazine structure in solid state. In the solution, a three-component ring-chain equilibrium is established between the imine form and cis- and trans-oxazines. Over time or under heating, these compounds are prone to 2-azaallylic prototropic tautomerism, involving 1-(phenyl- (pyridinylmethylimino)methyl)naphthalen-2-ols in equilibrium.

Авторлар туралы

K. Metlushka

Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”

Email: alfonsov@yandex.ru
Ресей, 8 ul. Akad. Arbuzova, Kazan, 420088

D. Sadkova

Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”

Email: alfonsov@yandex.ru
Ресей, 8 ul. Akad. Arbuzova, Kazan, 420088

K. Nikitina

Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”

Email: alfonsov@yandex.ru
Ресей, 8 ul. Akad. Arbuzova, Kazan, 420088

Z. Yamaleeva

Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”

Email: alfonsov@yandex.ru
Ресей, 8 ul. Akad. Arbuzova, Kazan, 420088

K. Ivshin

Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”; Alexander Butlerov Institute of Chemistry, Kazan Federal University

Email: alfonsov@yandex.ru
Ресей, 8 ul. Akad. Arbuzova, Kazan, 420088; 18 ul. Kremlyevskaya, Kazan, 420008

O. Kataeva

Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”

Email: alfonsov@yandex.ru
Ресей, 8 ul. Akad. Arbuzova, Kazan, 420088

V. Alfonsov

Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”

Хат алмасуға жауапты Автор.
Email: alfonsov@yandex.ru
Ресей, 8 ul. Akad. Arbuzova, Kazan, 420088


© Springer Science+Business Media, LLC, part of Springer Nature, 2018

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