Email this article Condensation products of Betti base and pyridinecarboxaldehydes
- Authors: Metlushka K.E.1, Sadkova D.N.1, Nikitina K.A.1, Yamaleeva Z.R.1, Ivshin K.A.1,2, Kataeva O.N.1, Alfonsov V.A.1
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Affiliations:
- Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”
- Alexander Butlerov Institute of Chemistry, Kazan Federal University
- Issue: Vol 67, No 12 (2018)
- Pages: 2271-2274
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/243230
- DOI: https://doi.org/10.1007/s11172-018-2369-z
- ID: 243230
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Abstract
Previously unknown condensation products were obtained by the reaction of the racemic Betti base with 2-, 3- and 4-pyridinecarboxaldehydes. It was established that they have a naphthoxazine structure in solid state. In the solution, a three-component ring-chain equilibrium is established between the imine form and cis- and trans-oxazines. Over time or under heating, these compounds are prone to 2-azaallylic prototropic tautomerism, involving 1-(phenyl- (pyridinylmethylimino)methyl)naphthalen-2-ols in equilibrium.
About the authors
K. E. Metlushka
Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”
Email: alfonsov@yandex.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
D. N. Sadkova
Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”
Email: alfonsov@yandex.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
K. A. Nikitina
Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”
Email: alfonsov@yandex.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
Z. R. Yamaleeva
Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”
Email: alfonsov@yandex.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
K. A. Ivshin
Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”; Alexander Butlerov Institute of Chemistry, Kazan Federal University
Email: alfonsov@yandex.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088; 18 ul. Kremlyevskaya, Kazan, 420008
O. N. Kataeva
Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”
Email: alfonsov@yandex.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
V. A. Alfonsov
Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”
Author for correspondence.
Email: alfonsov@yandex.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
