Condensation products of Betti base and pyridinecarboxaldehydes


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Previously unknown condensation products were obtained by the reaction of the racemic Betti base with 2-, 3- and 4-pyridinecarboxaldehydes. It was established that they have a naphthoxazine structure in solid state. In the solution, a three-component ring-chain equilibrium is established between the imine form and cis- and trans-oxazines. Over time or under heating, these compounds are prone to 2-azaallylic prototropic tautomerism, involving 1-(phenyl- (pyridinylmethylimino)methyl)naphthalen-2-ols in equilibrium.

作者简介

K. Metlushka

Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”

Email: alfonsov@yandex.ru
俄罗斯联邦, 8 ul. Akad. Arbuzova, Kazan, 420088

D. Sadkova

Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”

Email: alfonsov@yandex.ru
俄罗斯联邦, 8 ul. Akad. Arbuzova, Kazan, 420088

K. Nikitina

Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”

Email: alfonsov@yandex.ru
俄罗斯联邦, 8 ul. Akad. Arbuzova, Kazan, 420088

Z. Yamaleeva

Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”

Email: alfonsov@yandex.ru
俄罗斯联邦, 8 ul. Akad. Arbuzova, Kazan, 420088

K. Ivshin

Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”; Alexander Butlerov Institute of Chemistry, Kazan Federal University

Email: alfonsov@yandex.ru
俄罗斯联邦, 8 ul. Akad. Arbuzova, Kazan, 420088; 18 ul. Kremlyevskaya, Kazan, 420008

O. Kataeva

Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”

Email: alfonsov@yandex.ru
俄罗斯联邦, 8 ul. Akad. Arbuzova, Kazan, 420088

V. Alfonsov

Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”

编辑信件的主要联系方式.
Email: alfonsov@yandex.ru
俄罗斯联邦, 8 ul. Akad. Arbuzova, Kazan, 420088

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