Email this article Synthesis of substituted fulvenes with inden-2-ylphosphonic acid fragments
- Authors: Prishchenko A.A.1, Livantsov M.V.1, Novikova O.P.1, Livantsova L.I.1, Petrosyan V.S.1
-
Affiliations:
- Department of Chemistry, M. V. Lomonosov Moscow State University
- Issue: Vol 66, No 7 (2017)
- Pages: 1261-1264
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/240965
- DOI: https://doi.org/10.1007/s11172-017-1882-9
- ID: 240965
Cite item
Open Access
Access granted
Subscription Access
Abstract
We have developed preparative methods for the synthesis of substituted fulvenes including inden-2-ylphosphonic acid fragments, as well as aromatic and heterocyclic substituents, based on bis(trimethylsilyl)inden-2-ylphosphonate and substituted azomethines in the presence of sodium hydride as an efficient initiator of the reaction. Subsequent treatment of the phosphonates with methanolic solution of sodium methoxide furnished water-soluble disodium salts of the corresponding phosphonic acids.
About the authors
A. A. Prishchenko
Department of Chemistry, M. V. Lomonosov Moscow State University
Author for correspondence.
Email: aprishchenko@yandex.ru
Russian Federation, Build. 3, 1 Leninskie Gory, Moscow, 119991
M. V. Livantsov
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: aprishchenko@yandex.ru
Russian Federation, Build. 3, 1 Leninskie Gory, Moscow, 119991
O. P. Novikova
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: aprishchenko@yandex.ru
Russian Federation, Build. 3, 1 Leninskie Gory, Moscow, 119991
L. I. Livantsova
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: aprishchenko@yandex.ru
Russian Federation, Build. 3, 1 Leninskie Gory, Moscow, 119991
V. S. Petrosyan
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: aprishchenko@yandex.ru
Russian Federation, Build. 3, 1 Leninskie Gory, Moscow, 119991
