New chiral CuII complexes and their catalytic activity in enantioselective Henry reaction
- Authors: Veselovsky V.V.1, Zlokazov M.V.1
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Affiliations:
- N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
- Issue: Vol 65, No 2 (2016)
- Pages: 440-444
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/237130
- DOI: https://doi.org/10.1007/s11172-016-1318-y
- ID: 237130
Cite item
Abstract
New chiral polydentante ligands capable of complexation of Cu2+ ions were synthesized using readily available derivatives of (S)-proline, d-glyceraldehyde, and imidazole as the starting materials. The synthesized complexes are efficient catalysts for enantioselective nitroaldol condensation (the Henry reaction).
About the authors
V. V. Veselovsky
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: ves@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991
M. V. Zlokazov
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: ves@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991