New chiral Cu II  complexes and their catalytic activity in enantioselective Henry reaction

V. V. Veselovsky; M. V. Zlokazov

doi:10.1007/s11172-016-1318-y

New chiral Cu^II complexes and their catalytic activity in enantioselective Henry reaction

Autores: Veselovsky V.¹, Zlokazov M.¹
Afiliações:
1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Edição: Volume 65, Nº 2 (2016)
Páginas: 440-444
Seção: Full Articles
URL: https://journals.rcsi.science/1066-5285/article/view/237130
DOI: https://doi.org/10.1007/s11172-016-1318-y
ID: 237130

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Resumo

New chiral polydentante ligands capable of complexation of Cu²⁺ ions were synthesized using readily available derivatives of (S)-proline, d-glyceraldehyde, and imidazole as the starting materials. The synthesized complexes are efficient catalysts for enantioselective nitroaldol condensation (the Henry reaction).

Sobre autores

V. Veselovsky

N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Autor responsável pela correspondência
Email: ves@ioc.ac.ru
Rússia, 47 Leninsky prosp., Moscow, 119991

M. Zlokazov