New chiral CuII complexes and their catalytic activity in enantioselective Henry reaction


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Abstract

New chiral polydentante ligands capable of complexation of Cu2+ ions were synthesized using readily available derivatives of (S)-proline, d-glyceraldehyde, and imidazole as the starting materials. The synthesized complexes are efficient catalysts for enantioselective nitroaldol condensation (the Henry reaction).

About the authors

V. V. Veselovsky

N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Author for correspondence.
Email: ves@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991

M. V. Zlokazov

N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Email: ves@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991


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