Synthesis and reactivity of metal-containing monomers 76. Nanostructured materials obtained by controlled thermolysis of Ni, Co, and Cu chelate complexes with azomethine ligands
- Authors: Golubeva N.D.1, Shilov G.V.1, Dzhavadyan E.A.1, Burlov A.S.2, Mashchenko S.A.2, Garnovskii D.A.3, Pomogailo A.D.1, Dzhardimalieva G.I.1, Pomogailo S.I.1
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Affiliations:
- Institute of Problems of Chemical Physics, Russian Academy of Sciences
- Research Institute of Physical and Organic Chemistry, Southern Federal University
- Southern Scientific Center
- Issue: Vol 65, No 1 (2016)
- Pages: 139-150
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/236853
- DOI: https://doi.org/10.1007/s11172-016-1276-4
- ID: 236853
Cite item
Abstract
The controlled thermolysis of mono(NiII, CuII, and CoII) and dinuclear (NiII, CuII, and FeII) chelate complexes with azomethine ligands, containing oxygen, nitrogen, and sulfur atoms in the chelate rings, was studied. The effect of the ligand environment on the thermal stability and composition of the resulting nanocomposites was examined. Comparative thermal analysis (DSC, DTA, and TGA) of the metal chelate complexes was performed. Their thermolysis products were characterized using elemental analysis, X-ray powder diffraction, scanning electron microscopy, and gel permeation chromatography. The magnetic properties of the nanocomposites obtained were analyzed.
About the authors
N. D. Golubeva
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: dzhardim@icp.ac.ru
Russian Federation, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
G. V. Shilov
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: dzhardim@icp.ac.ru
Russian Federation, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
E. A. Dzhavadyan
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: dzhardim@icp.ac.ru
Russian Federation, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
A. S. Burlov
Research Institute of Physical and Organic Chemistry, Southern Federal University
Email: dzhardim@icp.ac.ru
Russian Federation, 194/2 prosp. Stachki, Rostov-on-Don, 344090
S. A. Mashchenko
Research Institute of Physical and Organic Chemistry, Southern Federal University
Email: dzhardim@icp.ac.ru
Russian Federation, 194/2 prosp. Stachki, Rostov-on-Don, 344090
D. A. Garnovskii
Southern Scientific Center
Email: dzhardim@icp.ac.ru
Russian Federation, 41 ul. Chekhova, Rostov-on-Don, 344006
A. D. Pomogailo
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: dzhardim@icp.ac.ru
Russian Federation, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
G. I. Dzhardimalieva
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Author for correspondence.
Email: dzhardim@icp.ac.ru
Russian Federation, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
S. I. Pomogailo
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: dzhardim@icp.ac.ru
Russian Federation, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432