Synthesis and reactivity of metal-containing monomers 76. Nanostructured materials obtained by controlled thermolysis of Ni, Co, and Cu chelate complexes with azomethine ligands
- 作者: Golubeva N.1, Shilov G.1, Dzhavadyan E.1, Burlov A.2, Mashchenko S.2, Garnovskii D.3, Pomogailo A.1, Dzhardimalieva G.1, Pomogailo S.1
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隶属关系:
- Institute of Problems of Chemical Physics, Russian Academy of Sciences
- Research Institute of Physical and Organic Chemistry, Southern Federal University
- Southern Scientific Center
- 期: 卷 65, 编号 1 (2016)
- 页面: 139-150
- 栏目: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/236853
- DOI: https://doi.org/10.1007/s11172-016-1276-4
- ID: 236853
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详细
The controlled thermolysis of mono(NiII, CuII, and CoII) and dinuclear (NiII, CuII, and FeII) chelate complexes with azomethine ligands, containing oxygen, nitrogen, and sulfur atoms in the chelate rings, was studied. The effect of the ligand environment on the thermal stability and composition of the resulting nanocomposites was examined. Comparative thermal analysis (DSC, DTA, and TGA) of the metal chelate complexes was performed. Their thermolysis products were characterized using elemental analysis, X-ray powder diffraction, scanning electron microscopy, and gel permeation chromatography. The magnetic properties of the nanocomposites obtained were analyzed.
作者简介
N. Golubeva
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: dzhardim@icp.ac.ru
俄罗斯联邦, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
G. Shilov
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: dzhardim@icp.ac.ru
俄罗斯联邦, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
E. Dzhavadyan
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: dzhardim@icp.ac.ru
俄罗斯联邦, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
A. Burlov
Research Institute of Physical and Organic Chemistry, Southern Federal University
Email: dzhardim@icp.ac.ru
俄罗斯联邦, 194/2 prosp. Stachki, Rostov-on-Don, 344090
S. Mashchenko
Research Institute of Physical and Organic Chemistry, Southern Federal University
Email: dzhardim@icp.ac.ru
俄罗斯联邦, 194/2 prosp. Stachki, Rostov-on-Don, 344090
D. Garnovskii
Southern Scientific Center
Email: dzhardim@icp.ac.ru
俄罗斯联邦, 41 ul. Chekhova, Rostov-on-Don, 344006
A. Pomogailo
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: dzhardim@icp.ac.ru
俄罗斯联邦, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
G. Dzhardimalieva
Institute of Problems of Chemical Physics, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: dzhardim@icp.ac.ru
俄罗斯联邦, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
S. Pomogailo
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: dzhardim@icp.ac.ru
俄罗斯联邦, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432