Synthesis and reactivity of metal-containing monomers 76. Nanostructured materials obtained by controlled thermolysis of Ni, Co, and Cu chelate complexes with azomethine ligands
- Авторы: Golubeva N.1, Shilov G.1, Dzhavadyan E.1, Burlov A.2, Mashchenko S.2, Garnovskii D.3, Pomogailo A.1, Dzhardimalieva G.1, Pomogailo S.1
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Учреждения:
- Institute of Problems of Chemical Physics, Russian Academy of Sciences
- Research Institute of Physical and Organic Chemistry, Southern Federal University
- Southern Scientific Center
- Выпуск: Том 65, № 1 (2016)
- Страницы: 139-150
- Раздел: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/236853
- DOI: https://doi.org/10.1007/s11172-016-1276-4
- ID: 236853
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Аннотация
The controlled thermolysis of mono(NiII, CuII, and CoII) and dinuclear (NiII, CuII, and FeII) chelate complexes with azomethine ligands, containing oxygen, nitrogen, and sulfur atoms in the chelate rings, was studied. The effect of the ligand environment on the thermal stability and composition of the resulting nanocomposites was examined. Comparative thermal analysis (DSC, DTA, and TGA) of the metal chelate complexes was performed. Their thermolysis products were characterized using elemental analysis, X-ray powder diffraction, scanning electron microscopy, and gel permeation chromatography. The magnetic properties of the nanocomposites obtained were analyzed.
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N. Golubeva
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: dzhardim@icp.ac.ru
Россия, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
G. Shilov
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: dzhardim@icp.ac.ru
Россия, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
E. Dzhavadyan
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: dzhardim@icp.ac.ru
Россия, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
A. Burlov
Research Institute of Physical and Organic Chemistry, Southern Federal University
Email: dzhardim@icp.ac.ru
Россия, 194/2 prosp. Stachki, Rostov-on-Don, 344090
S. Mashchenko
Research Institute of Physical and Organic Chemistry, Southern Federal University
Email: dzhardim@icp.ac.ru
Россия, 194/2 prosp. Stachki, Rostov-on-Don, 344090
D. Garnovskii
Southern Scientific Center
Email: dzhardim@icp.ac.ru
Россия, 41 ul. Chekhova, Rostov-on-Don, 344006
A. Pomogailo
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: dzhardim@icp.ac.ru
Россия, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
G. Dzhardimalieva
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Автор, ответственный за переписку.
Email: dzhardim@icp.ac.ru
Россия, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
S. Pomogailo
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: dzhardim@icp.ac.ru
Россия, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432