A new PbII(ethylenediaminetetraacetate) coordination polymer with a two-dimensional layer structure
- Autores: Zhao D.1, Zhang R.1, Li F.1
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Afiliações:
- Department of Physics and Chemistry
- Edição: Volume 61, Nº 7 (2016)
- Páginas: 1077-1080
- Seção: Structure of Organic Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/190494
- DOI: https://doi.org/10.1134/S1063774516070142
- ID: 190494
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Resumo
A new PbII−edta4– coordination polymer, Pb2(edta)(H2O)0.76 (edta4– = ethylenediaminetetraacetate) was synthesized under hydrothermal condition. Single crystal X-ray analysis reveals that it represents a novel two-dimensional (2D) Pb2+–edta4– layer structure with a (4,82)-topology. Each edta4– ligand employs its four carboxylate O and two N atoms to chelate one PbII atom (hexa-coordinated) and connects five PbII atoms (ennea-coordinated) via its four carboxylate groups to form 2D layer framework. Adjacent layers are packed into the overall structure through vander Waals interactions.
Sobre autores
D. Zhao
Department of Physics and Chemistry
Autor responsável pela correspondência
Email: iamzd@hpu.edu.cn
República Popular da China, Jiaozuo, 454000
R. Zhang
Department of Physics and Chemistry
Email: iamzd@hpu.edu.cn
República Popular da China, Jiaozuo, 454000
F. Li
Department of Physics and Chemistry
Email: iamzd@hpu.edu.cn
República Popular da China, Jiaozuo, 454000