A new PbII(ethylenediaminetetraacetate) coordination polymer with a two-dimensional layer structure
- Авторлар: Zhao D.1, Zhang R.1, Li F.1
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Мекемелер:
- Department of Physics and Chemistry
- Шығарылым: Том 61, № 7 (2016)
- Беттер: 1077-1080
- Бөлім: Structure of Organic Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/190494
- DOI: https://doi.org/10.1134/S1063774516070142
- ID: 190494
Дәйексөз келтіру
Аннотация
A new PbII−edta4– coordination polymer, Pb2(edta)(H2O)0.76 (edta4– = ethylenediaminetetraacetate) was synthesized under hydrothermal condition. Single crystal X-ray analysis reveals that it represents a novel two-dimensional (2D) Pb2+–edta4– layer structure with a (4,82)-topology. Each edta4– ligand employs its four carboxylate O and two N atoms to chelate one PbII atom (hexa-coordinated) and connects five PbII atoms (ennea-coordinated) via its four carboxylate groups to form 2D layer framework. Adjacent layers are packed into the overall structure through vander Waals interactions.
Авторлар туралы
D. Zhao
Department of Physics and Chemistry
Хат алмасуға жауапты Автор.
Email: iamzd@hpu.edu.cn
ҚХР, Jiaozuo, 454000
R. Zhang
Department of Physics and Chemistry
Email: iamzd@hpu.edu.cn
ҚХР, Jiaozuo, 454000
F. Li
Department of Physics and Chemistry
Email: iamzd@hpu.edu.cn
ҚХР, Jiaozuo, 454000