A new PbII(ethylenediaminetetraacetate) coordination polymer with a two-dimensional layer structure
- 作者: Zhao D.1, Zhang R.1, Li F.1
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隶属关系:
- Department of Physics and Chemistry
- 期: 卷 61, 编号 7 (2016)
- 页面: 1077-1080
- 栏目: Structure of Organic Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/190494
- DOI: https://doi.org/10.1134/S1063774516070142
- ID: 190494
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详细
A new PbII−edta4– coordination polymer, Pb2(edta)(H2O)0.76 (edta4– = ethylenediaminetetraacetate) was synthesized under hydrothermal condition. Single crystal X-ray analysis reveals that it represents a novel two-dimensional (2D) Pb2+–edta4– layer structure with a (4,82)-topology. Each edta4– ligand employs its four carboxylate O and two N atoms to chelate one PbII atom (hexa-coordinated) and connects five PbII atoms (ennea-coordinated) via its four carboxylate groups to form 2D layer framework. Adjacent layers are packed into the overall structure through vander Waals interactions.
作者简介
D. Zhao
Department of Physics and Chemistry
编辑信件的主要联系方式.
Email: iamzd@hpu.edu.cn
中国, Jiaozuo, 454000
R. Zhang
Department of Physics and Chemistry
Email: iamzd@hpu.edu.cn
中国, Jiaozuo, 454000
F. Li
Department of Physics and Chemistry
Email: iamzd@hpu.edu.cn
中国, Jiaozuo, 454000