Vol 61, No 7 (2016)
- Year: 2016
- Articles: 14
- URL: https://journals.rcsi.science/1063-7745/issue/view/11945
Diffraction and Scattering of Ionizing Radiations
X-ray plane-wave diffraction effects in a crystal with third-order nonlinearity
Abstract
The two-wave dynamical diffraction in the Laue geometry has been theoretically considered for a plane X-ray wave in a crystal with a third-order nonlinear response to the external field. An analytical solution to the problem stated is found for certain diffraction conditions. A nonlinear pendulum effect is analyzed. The nonlinear extinction length is found to depend on the incident-wave intensity. A pendulum effect of a new type is revealed: the intensities of the transmitted and diffracted waves periodically depend on the incidentwave intensity at a fixed crystal thickness. The rocking curves and Borrmann nonlinear effect are numerically calculated.
Structure of Inorganic Compounds
Crystalline structure of Cu4SSe
Abstract
Ternary compound Cu4SSe has been first synthesized by alloying the Cu, S, and Se elements taken in stoichiometric ratios. An X-ray diffraction study of polycrystalline samples has revealed the synthesized material to be crystallized into the trigonal system with unit-cell parameters а = 4.021(1) Å, с = 6.838(1) Å, and V = 95.75(4) Å3; sp. gr. P\(\bar 3\) m1; Z = 1; Dx = 6.333(3) g/cm3. The crystal structure has been solved and refined to the reliability factor RBragg = 0.40%.
Structure of Organic Compounds
X-ray crystallography of methyl (6-amino-5-cyano-2-methyl-4-(2-nitrophenyl)-4H-pyran)-3-carboxylate
Abstract
The organic carbonitrile namely methyl (6-amino-5-cyano-2-methyl-4-(2-nitrophenyl)-4H-pyran)- 3-carboxylate is synthesized via one-pot multi-component reaction at room temperature using commercially available urea as inexpensive and environmentally benign organo-catalyst and its crystal structure is determined by X-ray technique. The crystals are monoclinic, sp. gr. C2/c, a = 12.3069(8) Å, b = 9.7023(7) Å, c = 24.812(2) Å, β = 94.862(6)°, Z = 8. The dihedral angle between pyran and phenyl rings is 87.8(1)°; the pyran ring is almost planar The dihedral angle between the mean planes of phenyl ring and nitro group is 44.4(2)°. The crystal structure is stabilized by N−H···N and N−H···O hydrogen bonds. In addition, C−H···π interactions are also observed in the crystal structure.
Synthesis, spectroscopic characterization, and crystal structure of a novel indoline derivative
Abstract
A new indoline derivative, tert-butyl 2′-amino-3′-cyano-6′-methyl-2-oxospiro[indoline-3,4′-pyran]-5′-carboxylate is eco-friendly synthesized, and its spectral properties and X-ray crystal structure are studied. In the molecule, the oxindole and pyran moieties are perpendicular to each other. The crystal structure is stabilized by intermolecular N−H···O and intramolecular C−H···O hydrogen bonds. Centrosymmetric dimer units are formed by intermolecular N−H···O hydrogen bonds. In addition, one C−H···π interaction is also observed.
Synthesis and crystal structure of the iridium(I) carbene complex with a pair of hydrogen wing tips
Abstract
The iridium(I) cyclooctadiene complex with two (3-tert-butylimidazol-2-ylidene) ligands [(H-ImtBu)2Ir(COD)]+PF6− (C22H32PF6IrN4) has been prepared, and its crystal structure is determined by X-ray diffraction. Complex exhibits slightly distorted square planar configurations around the metal atom, which is coordinated by two H-ImtBu ligands and one cyclooctadiene group. The new iridium carbene complex has a pair of hydrogen wing tips. The Ir−Ccarbene bond lengths are 2.066(5) and 2.052(5) Å, and the bond angle C−Ir−C between these bonds is 95.54(19)°. The dihedral angle between two imidazol-2-ylidene rings is 86.42°.
Synthesis, structure, spectroscopic investigations, and computational studies of optically pure β-ketoamide
Abstract
Chemical preparation, X-ray single crystal diffraction, IR and NMR spectroscopic investigations of a novel nonlinear optical organic compound (C17H22NO2Cl) are described. The compound crystallizes in the orthorhombic system with the non-centrosymmetric sp. gr. P212121. In the crystal structure, molecules are interconnected by N–H…O hydrogen bonds forming infinite chains along a axis. The Hirshfeld surface and associated fingerprint plots of the compound are presented to explore the nature of intermolecular interactions and their relative contributions in building the solid-state architecture. The molecular HOMO–LUMO compositions and their respective energy gaps are also drawn to explain the activity of the compound. The first hyperpolarizability βtot of the title compound is determined using DFT calculations. The optical properties are also investigated by UV–Vis absorption spectrum.
Synthesis of 2-arylidenebenzocycloalkanones containing N-donor heterocyclic rings
Abstract
A series of 2-arylidenebenzocycloalkanones containing heterocyclic rings 1–8 were prepared and characterized by IR, 1H NMR and elemental analyses. X-ray diffraction study of 6 reveals that the cyclohexyl ring of the 3,4-dihydronaphthalen-1(2H)-one adopts a chair conformation with a maximum deviation of 0.547(3) Å and makes dihedral angles of 52.24(17)° and 11.23(16)°, respectively, with the benzene plane and the mean plane of the benzimidazole ring.
A new PbII(ethylenediaminetetraacetate) coordination polymer with a two-dimensional layer structure
Abstract
A new PbII−edta4– coordination polymer, Pb2(edta)(H2O)0.76 (edta4– = ethylenediaminetetraacetate) was synthesized under hydrothermal condition. Single crystal X-ray analysis reveals that it represents a novel two-dimensional (2D) Pb2+–edta4– layer structure with a (4,82)-topology. Each edta4– ligand employs its four carboxylate O and two N atoms to chelate one PbII atom (hexa-coordinated) and connects five PbII atoms (ennea-coordinated) via its four carboxylate groups to form 2D layer framework. Adjacent layers are packed into the overall structure through vander Waals interactions.
Synthesis, antityrosinase activity of curcumin analogues, and crystal structure of (1E,4E)-1,5-bis(4-ethoxyphenyl)penta-1,4-dien-3-one
Abstract
Five derivatives of curcumin analogue (R = OCH2CH3 (1), R = N(CH3)2 (2), R = 2,4,5-OCH3 (3), R = 2,4,6-OCH3 (4), and R = 3,4,5-OCH3 (5)) were synthesized and characterized by 1H NMR, FT-IR and UV–Vis spectroscopy. The synthesized derivatives were screened for antityrosinase activity, and found that 4 and 5 possess such activity. The crystal structure of 1 was determined by single crystal X-ray diffraction: monoclinic, sp. gr. P21/c, a = 17.5728(15) Å, b = 5.9121(5) Å, c = 19.8269(13) Å, β = 121.155(5)°, Z = 4. The molecule 1 is twisted with the dihedral angle between two phenyl rings being 15.68(10)°. In the crystal packing, the molecules 1 are linked into chains by C−H···π interactions and further stacked by π···π interactions with the centroid–centroid distance of 3.9311(13) Å.
Preparation, characterisation, and crystal structure analysis of (2E,2′E)-3,3′-(1,4-phenylene)bis(1-(2-aminophenyl)prop-2-en-1-one
Abstract
A novel bis-chalcone, (2E,2′E)-3,3′-(1,4-phenylene)bis(1-(2-aminophenyl)prop-2-en-1-one) is synthesized through a base catalyzed Claisen-Schmidt condensation reaction of terephthalaldehyde with 2-aminoacetophenone. Its structure (sp. gr. P\(\bar 1\) , Z = 2) is determined from single crystal X-ray diffraction data. There are two independent centrosymmetric molecules with no significant differences in bond lengths and angles between them. The NMR, IR, HRMS, and UV spectral data of the prepared bis-chalcone are presented.
Crystal structures of two organic salts of 1,2,3,4-tetrahydro-1,10-phenanthroline
Abstract
Two organic salts of 1,2,3,4-tetrahydro-1,10-phenanthroline (tphen), namely (oaH)(tphenH) (1) and (ssa)(tphenH)·H2O (2) (oaH2 is oxalic acid, ssaH is 5-sulfosalicylic acid), were synthesized and structurally characterized. Both compounds contain tphenH+ cations but illustrate different crystal structures. The tphenH+ cations show a cross-stacking packing model in 1 but display a herringbone packing model in 2.
Lattice Dynamics and Phase Transitions
Formation of structure in small lead clusters under thermal effect
Abstract
The thermal effect on lead clusters with radii up to 5.5 nm has been investigated by the molecular dynamics method using a modified tight-binding potential TB-SMA. The melting of Pb nanoparticles of these sizes is strictly homogeneous, without the formation of a surface liquidlike layer. The primary fcc phase in the particles is retained upon heating in the overwhelming majority of model experiments. An analysis of the structure formation during crystallization has shown that structures with pentagonal symmetry are preferred for lead clusters in this case. It is noted that an increase in the nanoparticle size leads to the dominance of the dodecahedral structure over the icosahedral one.
Structural transformations in Cu1.95Ni0.05S crystals
Abstract
A solid solution of the Cu1.95Ni0.05S composition has been synthesized for the first time due to the partial replacement of Cu with Ni atoms in Cu2S. The polymorphic transformations in the polycrystalline samples in the temperature range of 300–1400 K have been investigated by X-ray diffraction and differential thermal analysis. It is established that, at room temperature, the synthesized Cu1.95Ni0.05S samples have an orthorhombic lattice with unit-cell parameters a = 26.50 Å, b = 15.39 Å, and c = 13.85 Å (sp. gr. Abm2). Heating to T = 379 ± 2 K leads to its transformation into a hexagonal lattice with parameters a = 3.960 Å and c = 6.78 Å (sp. gr. P63/mmc). At 750 ± 2 K, the hexagonal modification is transformed into a cubic one with period a = 5.788 Å (sp. gr. Fm\(\bar 3\)m). The phase transition in this crystal is enantiotropic.
Nanomaterials, Ceramics
Synthesis of high aspect ratio ZnO nanowires with an inexpensive handcrafted electrochemical setup
Abstract
In this work, high aspect ratio zinc oxide nanowires are synthesized using templated one-step electrodeposition technique. Electrodeposition of the nanowires is done using a handcrafted electronic system. Nuclear track-etched polycarbonate membrane is used as a template to form the high aspect ratio nanowires. The result of X-ray diffraction and scanning electron microscopy shows that nanowires with a good crystallinity and an aspect ratio of more than 30 can be achieved in a suitable condition. The height of electrodeposited nanowires reaches to about 11 μm. Based on the obtained results, high aspect ratio ZnO nanowires can be formed using inexpensive electrodeposition setup with an acceptable quality.