Role of electronic effects in forming the structure of the nitrilotrismethylenephosphonic complexes of 3d elements (Cr–Zn)


Citar

Texto integral

Acesso aberto Acesso aberto
Acesso é fechado Acesso está concedido
Acesso é fechado Somente assinantes

Resumo

Two series of nitrilotrismethylenephosphonic complexes of 3d elements, [MII(H2O)3{NH(CH2PO3H)3}]n (M = Cr–Zn) and Na8[MII{N(CH2PO3)3}]2nH2O (M = Co–Zn), are studied. A comparative analysis of their structural features showed the influence the Jahn–Teller effect has on the formation of the crystal structures, reactive capacities, and anticorrosive activities of these compounds.

Sobre autores

F. Chausov

Udmurt State University; Physicotechnical Institute, Ural Branch; Institute of Mechanics, Ural Branch

Autor responsável pela correspondência
Email: chaus@udsu.ru
Rússia, Izhevsk, 426034; Izhevsk, 426001; Izhevsk, 426034

N. Somov

Lobachevsky National Research University

Email: chaus@udsu.ru
Rússia, Nizhny Novgorod, 607220

E. Naimushina

Udmurt State University; Izhevsk State Technical University

Email: chaus@udsu.ru
Rússia, Izhevsk, 426034; Izhevsk, 426069

I. Shabanova

Physicotechnical Institute, Ural Branch

Email: chaus@udsu.ru
Rússia, Izhevsk, 426001

Arquivos suplementares

Arquivos suplementares
Ação
1. JATS XML

Declaração de direitos autorais © Allerton Press, Inc., 2017