Role of electronic effects in forming the structure of the nitrilotrismethylenephosphonic complexes of 3d elements (Cr–Zn)


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Two series of nitrilotrismethylenephosphonic complexes of 3d elements, [MII(H2O)3{NH(CH2PO3H)3}]n (M = Cr–Zn) and Na8[MII{N(CH2PO3)3}]2nH2O (M = Co–Zn), are studied. A comparative analysis of their structural features showed the influence the Jahn–Teller effect has on the formation of the crystal structures, reactive capacities, and anticorrosive activities of these compounds.

作者简介

F. Chausov

Udmurt State University; Physicotechnical Institute, Ural Branch; Institute of Mechanics, Ural Branch

编辑信件的主要联系方式.
Email: chaus@udsu.ru
俄罗斯联邦, Izhevsk, 426034; Izhevsk, 426001; Izhevsk, 426034

N. Somov

Lobachevsky National Research University

Email: chaus@udsu.ru
俄罗斯联邦, Nizhny Novgorod, 607220

E. Naimushina

Udmurt State University; Izhevsk State Technical University

Email: chaus@udsu.ru
俄罗斯联邦, Izhevsk, 426034; Izhevsk, 426069

I. Shabanova

Physicotechnical Institute, Ural Branch

Email: chaus@udsu.ru
俄罗斯联邦, Izhevsk, 426001

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