Email this article Role of electronic effects in forming the structure of the nitrilotrismethylenephosphonic complexes of 3d elements (Cr–Zn)
- Authors: Chausov F.F.1,2,3, Somov N.V.4, Naimushina E.A.1,5, Shabanova I.N.2
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Affiliations:
- Udmurt State University
- Physicotechnical Institute, Ural Branch
- Institute of Mechanics, Ural Branch
- Lobachevsky National Research University
- Izhevsk State Technical University
- Issue: Vol 81, No 3 (2017)
- Pages: 285-287
- Section: Proceedings of the “OMA-19”, “ODPO-19”
- URL: https://journals.rcsi.science/1062-8738/article/view/184991
- DOI: https://doi.org/10.3103/S1062873817030078
- ID: 184991
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Abstract
Two series of nitrilotrismethylenephosphonic complexes of 3d elements, [MII(H2O)3{NH(CH2PO3H)3}]n (M = Cr–Zn) and Na8[MII{N(CH2PO3)3}]2nH2O (M = Co–Zn), are studied. A comparative analysis of their structural features showed the influence the Jahn–Teller effect has on the formation of the crystal structures, reactive capacities, and anticorrosive activities of these compounds.
About the authors
F. F. Chausov
Udmurt State University; Physicotechnical Institute, Ural Branch; Institute of Mechanics, Ural Branch
Author for correspondence.
Email: chaus@udsu.ru
Russian Federation, Izhevsk, 426034; Izhevsk, 426001; Izhevsk, 426034
N. V. Somov
Lobachevsky National Research University
Email: chaus@udsu.ru
Russian Federation, Nizhny Novgorod, 607220
E. A. Naimushina
Udmurt State University; Izhevsk State Technical University
Email: chaus@udsu.ru
Russian Federation, Izhevsk, 426034; Izhevsk, 426069
I. N. Shabanova
Physicotechnical Institute, Ural Branch
Email: chaus@udsu.ru
Russian Federation, Izhevsk, 426001
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