Mechanism of reaction of selenium elimination in diacetophenonyl selenide under the action of reduced glutathione

P. A. Poluboyarinov; P. P. Leshchenko; I. Ya. Moiseeva; S. G. Kolesnikova; N. B. Epshtein

doi:10.1134/S1061934817070103

Mechanism of reaction of selenium elimination in diacetophenonyl selenide under the action of reduced glutathione

作者: Poluboyarinov P.¹, Leshchenko P.¹, Moiseeva I.², Kolesnikova S.³, Epshtein N.³
隶属关系:
1. Penza State University of Architecture and Construction
2. Penza State University
3. National Research Nuclear University MEPhI
期: 卷 72, 编号 7 (2017)
页面: 739-744
栏目: Articles
URL: https://journals.rcsi.science/1061-9348/article/view/182544
DOI: https://doi.org/10.1134/S1061934817070103
ID: 182544

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Products of reaction between the organoselenium xenobiotic, diacetophenonyl selenide (1,5-diphenyl-3-selenapenta-1,5-dione), and reduced glutathione at different molar ratios and pH values were studied by HPLC and TLC. Reaction intermediates, S-(acetophenylselenyl)glutathione and glutathione selenodisulfide, and reaction products, acetophenone and hydroselenide anion, were detected. The reaction scheme proposed earlier was confirmed.