Simultaneous determination of aliphatic acids and aldehydes in aqueous media by reaction gas chromatography


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Resumo

A procedure is developed for the gas chromatographic determination of lower aldehydes as dibutoxyalkanes and carboxylic acids as butyl esters by the reaction with tributyl borate in an aqueous medium. Derivatization conditions were optimized. The procedure was used to determine side products in glyoxal synthesized by the catalytic oxidation of ethylene glycol.

Sobre autores

M. Pervova

Institute of Organic Synthesis, Ural Branch

Autor responsável pela correspondência
Email: pervova@ios.uran.ru
Rússia, ul. S. Kovalevskoi 22/Akademicheskaya 20, Yekaterinburg, 620990

D. Chizhov

Institute of Organic Synthesis, Ural Branch

Email: pervova@ios.uran.ru
Rússia, ul. S. Kovalevskoi 22/Akademicheskaya 20, Yekaterinburg, 620990

V. Saloutin

Institute of Organic Synthesis, Ural Branch

Email: pervova@ios.uran.ru
Rússia, ul. S. Kovalevskoi 22/Akademicheskaya 20, Yekaterinburg, 620990


Declaração de direitos autorais © Pleiades Publishing, Ltd., 2016

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