Study of the Products of the Mechanochemical Activation of Teflon in a Mixture with Metals by Chromatography-Mass Spectrometry and Thermodesorption Mass Spectrometry


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Abstract

Mass spectrometry and chromatography are used to study the decomposition products of Teflon mixtures of the “Fluralite-4” brand with magnesium, tungsten, and titanium, activated by mechanochemistry. The temperature and energy parameters of water and carbon dioxide release are determined, volatile products of Teflon depolymerization are detected and identified, i.e., tetrafluoroethylene, trifluoromethylene, trifluoroethylene. It is shown that the introduction of metal mixtures in the composition significantly affects the decomposition processes of Teflon.

About the authors

A. V. Ul’yanov

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: akburyak@mail.ru
Russian Federation, Moscow, 119071

O. G. Tataurova

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: akburyak@mail.ru
Russian Federation, Moscow, 119071

D. A. Popov

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: akburyak@mail.ru
Russian Federation, Moscow, 119071

Yu. P. Toporov

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: akburyak@mail.ru
Russian Federation, Moscow, 119071

A. I. Malkin

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: akburyak@mail.ru
Russian Federation, Moscow, 119071

A. K. Buryak

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Author for correspondence.
Email: akburyak@mail.ru
Russian Federation, Moscow, 119071


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