Study of the Products of the Mechanochemical Activation of Teflon in a Mixture with Metals by Chromatography-Mass Spectrometry and Thermodesorption Mass Spectrometry


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Resumo

Mass spectrometry and chromatography are used to study the decomposition products of Teflon mixtures of the “Fluralite-4” brand with magnesium, tungsten, and titanium, activated by mechanochemistry. The temperature and energy parameters of water and carbon dioxide release are determined, volatile products of Teflon depolymerization are detected and identified, i.e., tetrafluoroethylene, trifluoromethylene, trifluoroethylene. It is shown that the introduction of metal mixtures in the composition significantly affects the decomposition processes of Teflon.

Sobre autores

A. Ul’yanov

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: akburyak@mail.ru
Rússia, Moscow, 119071

O. Tataurova

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: akburyak@mail.ru
Rússia, Moscow, 119071

D. Popov

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: akburyak@mail.ru
Rússia, Moscow, 119071

Yu. Toporov

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: akburyak@mail.ru
Rússia, Moscow, 119071

A. Malkin

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: akburyak@mail.ru
Rússia, Moscow, 119071

A. Buryak

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Autor responsável pela correspondência
Email: akburyak@mail.ru
Rússia, Moscow, 119071


Declaração de direitos autorais © Pleiades Publishing, Inc., 2019

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