Silylation with the Generation of a Fixed Charge for the Analysis of Alcohols by MALDI and SALDI Mass Spectrometry
- Authors: Zhilyaev D.I.1, Voskresensky L.G.1, Polovkov N.Y.2, Borisov R.S.1,2
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Affiliations:
- People’s Friendship University of Russia
- Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
- Issue: Vol 73, No 14 (2018)
- Pages: 1323-1326
- Section: Articles
- URL: https://journals.rcsi.science/1061-9348/article/view/182920
- DOI: https://doi.org/10.1134/S1061934818140149
- ID: 182920
Cite item
Abstract
A new method of the derivatization of alcohols for their analysis by matrix-assisted laser desorption/ionization (MALDI) and surface-assisted laser desorption/ionization (SALDI) is proposed. The approach is based on the silylation of the analytes with bromomethylchlorodimethylsilane in the presence of tertiary amines to yield fixed-charge containing derivatives. The proposed method was tested using aliphatic alcohols, terpenols, and sterols. MALDI and SALDI mass spectra of all derivatives contain intense ion peaks corresponding to their cationic parts.
Keywords
About the authors
D. I. Zhilyaev
People’s Friendship University of Russia
Author for correspondence.
Email: dimzhi@mail.ru
Russian Federation, Moscow, 117198
L. G. Voskresensky
People’s Friendship University of Russia
Email: dimzhi@mail.ru
Russian Federation, Moscow, 117198
N. Yu. Polovkov
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Email: dimzhi@mail.ru
Russian Federation, Moscow, 119991
R. S. Borisov
People’s Friendship University of Russia; Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Email: dimzhi@mail.ru
Russian Federation, Moscow, 117198; Moscow, 119991
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