Email this article Determination of the structural features of O-alkyl-S-2-(N,N-dialkylamino) ethyl alkylthiophosphonates from their electron ionization mass spectra
- Authors: Terentyev A.G.1, Morozik Y.I.1,2, Rybal’chenko I.V.2, Dudkin A.V.1, Smirnov A.O.1, Galyaev G.V.1
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Affiliations:
- Military Academy of Nuclear, Biological, and Chemical Defence
- Kostroma State Technological University
- Issue: Vol 71, No 13 (2016)
- Pages: 1266-1274
- Section: Articles
- URL: https://journals.rcsi.science/1061-9348/article/view/182223
- DOI: https://doi.org/10.1134/S1061934816130104
- ID: 182223
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Abstract
It is believed that information about the molecular structure of highly toxic O-alkyl-S-2(N,N-dialkylamino) ethyl alkylthiophosphonates (V-gases) obtained from their EI mass spectra is too insufficient. In particular, the determination of molecular weights and structures of radicals at phosphorus and oxygen atoms causes great difficulties. In this paper, solutions of these problems are proposed.
About the authors
A. G. Terentyev
Military Academy of Nuclear, Biological, and Chemical Defence
Author for correspondence.
Email: tag2278@mail.ru
Russian Federation, ul. Gor’kogo 16, Kostroma, 156015
Yu. I. Morozik
Military Academy of Nuclear, Biological, and Chemical Defence; Kostroma State Technological University
Email: tag2278@mail.ru
Russian Federation, ul. Gor’kogo 16, Kostroma, 156015; ul. Dzerzhinskogo 17, Kostroma, 156001
I. V. Rybal’chenko
Kostroma State Technological University
Email: tag2278@mail.ru
Russian Federation, ul. Dzerzhinskogo 17, Kostroma, 156001
A. V. Dudkin
Military Academy of Nuclear, Biological, and Chemical Defence
Email: tag2278@mail.ru
Russian Federation, ul. Gor’kogo 16, Kostroma, 156015
A. O. Smirnov
Military Academy of Nuclear, Biological, and Chemical Defence
Email: tag2278@mail.ru
Russian Federation, ul. Gor’kogo 16, Kostroma, 156015
G. V. Galyaev
Military Academy of Nuclear, Biological, and Chemical Defence
Email: tag2278@mail.ru
Russian Federation, ul. Gor’kogo 16, Kostroma, 156015
