Determination of the structural features of O-alkyl-S-2-(N,N-dialkylamino) ethyl alkylthiophosphonates from their electron ionization mass spectra


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It is believed that information about the molecular structure of highly toxic O-alkyl-S-2(N,N-dialkylamino) ethyl alkylthiophosphonates (V-gases) obtained from their EI mass spectra is too insufficient. In particular, the determination of molecular weights and structures of radicals at phosphorus and oxygen atoms causes great difficulties. In this paper, solutions of these problems are proposed.

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A. Terentyev

Military Academy of Nuclear, Biological, and Chemical Defence

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俄罗斯联邦, ul. Gor’kogo 16, Kostroma, 156015

Yu. Morozik

Military Academy of Nuclear, Biological, and Chemical Defence; Kostroma State Technological University

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俄罗斯联邦, ul. Gor’kogo 16, Kostroma, 156015; ul. Dzerzhinskogo 17, Kostroma, 156001

I. Rybal’chenko

Kostroma State Technological University

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俄罗斯联邦, ul. Dzerzhinskogo 17, Kostroma, 156001

A. Dudkin

Military Academy of Nuclear, Biological, and Chemical Defence

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俄罗斯联邦, ul. Gor’kogo 16, Kostroma, 156015

A. Smirnov

Military Academy of Nuclear, Biological, and Chemical Defence

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俄罗斯联邦, ul. Gor’kogo 16, Kostroma, 156015

G. Galyaev

Military Academy of Nuclear, Biological, and Chemical Defence

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俄罗斯联邦, ul. Gor’kogo 16, Kostroma, 156015


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