Effect of Magnetron Sputtering Power on ITO Film Deposition at Room Temperature

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

Magnetron sputtering in the medium frequency (MF) mode was used to obtain ITO films on glass substrates at room temperature in an oxygen-free environment. The effect of the magnetron sputtering power on the electrophysical properties and surface morphology of ITO films is studied. It is shown that the ITO film deposition rate depends linearly on the power of magnetron sputtering in the MF mode. It is found that ITO films have a predominantly nanocrystalline structure at a magnetron sputtering power of more than 100 W. Increasing the sputtering power leads to an increase in surface roughness from 13.5 to 24.6 nm and grain size from 11.7 to 27.5 nm in the ITO film. The minimum resistivity of the ITO films is 6.82 × 10–4 Ω cm at the concentration and mobility of charge carriers of 2.48 × 1020 cm–3 and 36.8 cm2/V s, which corresponds to the optimum power of magnetron sputtering of 200 W. The results obtained correspond to a high level of surface resistance values for ITO films (34.1 Ω/□), which can be used to form transparent conducting electrodes in solar cells and memristors, both on glass and flexible substrates.

About the authors

A. V. Saenko

Institute of Nanotechnologies, Electronics, and Equipment Engineering, Southern Federal University

Email: avsaenko@sfedu.ru
Taganrog, 347928 Russia

Z. E. Vakulov

Institute of Nanotechnologies, Electronics, and Equipment Engineering, Southern Federal University

Email: avsaenko@sfedu.ru
Taganrog, 347928 Russia

V. S. Klimin

Institute of Nanotechnologies, Electronics, and Equipment Engineering, Southern Federal University

Email: avsaenko@sfedu.ru
Taganrog, 347928 Russia

G. E. Bilyk

Institute of Nanotechnologies, Electronics, and Equipment Engineering, Southern Federal University

Email: avsaenko@sfedu.ru
Taganrog, 347928 Russia

S. P. Malyukov

Institute of Nanotechnologies, Electronics, and Equipment Engineering, Southern Federal University

Author for correspondence.
Email: avsaenko@sfedu.ru
Taganrog, 347928 Russia

References

  1. Amador Perez-Tomas. Functional Oxides for Photoneuromorphic Engineering: Toward a Solar Brain // Adv. Mater. Interfaces. 2019. V. 6. P. 1900471.
  2. Jago Txintxurreta, Eva G-Berasategui, Rocio Ortiz, Oihane Hernandez, Lucia Mendizábal, Javier Barriga. Indium Tin Oxide Thin Film Deposition by Magnetron Sputtering at Room Temperature for the Manufacturing of Efficient Transparent Heaters // Coatings. 2021. V. 11. P. 92.
  3. Marikkannan M., Subramanian M., Mayandi J., Tanemura M., Vishnukanthan V., Pearce J.M. Effect of ambient combinations of argon, oxygen, and hydrogen on the properties of DC magnetron sputtered indium tin oxide films // AIP Advances. 2015. V. 5. P. 017128.
  4. Abdelaziz Tchenka, Abdelali Agdad, Mohamed Cheikh Samba Vall, Salma Kaotar Hnawi, Abdelfattah Narjis, Lahcen Nkhaili, Elalami Ibnouelghazi, Elmaati Ech-Chamikh. Effect of RF Sputtering Power and Deposition Time on Optical and Electrical Properties of Indium Tin Oxide Thin Film // Advances in Materials Science and Engineering. 2021. P. 1–14.
  5. Goncharov E.V., Sayenko A.V., Malyukov S.P., Palii A.V. Formation of ITO Thin Films by MF Magnetron Sputtering for Solar Cells Application // Proceedings of ITN-T 2021 – 7th IEEE International Conference on Information Technology and Nanotechnology, 2021.
  6. Amalraj Peter Amalathas, Maan M. Alkaisi. Effects of film thickness and sputtering power on properties of ITO thin films deposited by RF magnetron sputtering without oxygen // J. Mater Sci.: Mater Electron, 2016. V. 27. P. 11064–11071.
  7. Chih-hao Yang, Shih-chin Lee, Tien-chai Lin, Suz-cheng Chen. Electrical and optical properties of indium tin oxide films prepared on plastic substrates by radio frequency magnetron sputtering // Thin Solid Films. 2008. V. 516. P. 1984–1991.
  8. Jae-Ho Kim, Hae-Jun Seok, Hyeong-Jin Seo, Tae-Yeon Seong, Jin Hyuck Heo, Sang-Hyuk Lim, Kyung-Jun Ahnd, Han-Ki Kim. Flexible ITO films with atomically flat surfaces for high performance flexible perovskite solar cells // Nanoscale. 2018. V. 10. P. 20587–20598.
  9. Hyung-Jin Choi, Soon-Gil Yoon, Ju-Ho Lee, Jeong-Yong Lee. Crystallized Indium-Tin Oxide (ITO) Thin Films Grown at Low Temperature onto Flexible Polymer Substrates // ECS J. Solid State Science and Technology. 2012. V. 1(5). P. 106–109.
  10. Kelly P.J., Henderson P.S., Arnell R.D., Roche G.A., Carter D. Reactive pulsed magnetron sputtering process for alumina films // J. Vacuum Science and Technology A. 2000. V. 18. № 6. P. 2890–2896.
  11. Bradley J.W., Karkari S.K., Vetushka A. A study of the transient plasma potential in a pulsed bipolar dc magnetron discharge // Plasma Sources Sci. Technol. 2004. V. 13. P. 189–198.
  12. Miaoju Chuang. ITO Films Prepared by Long-throw Magnetron Sputtering without Oxygen Partial Pressure // J. Mater. Sci. Technol. 2010. V. 26(7). P. 577–583.
  13. Guillen C., Herrero J. Polycrystalline growth and recrystallization processes in sputtered ITO thin films // Thin Solid Films. 2006. V. 510. P. 260–264.
  14. Kudryashov D., Gudovskikh A., Zelentsov K. Low temperature growth of ITO transparent conductive oxide layers in oxygen-free environment by RF magnetron sputtering // J. Physics: Conference Series. 2013. V. 461. P. 012021.
  15. Kosariana A., Shakiba M., Farshidi E. Role of Sputtering Power on the Microstructural and Electro-Optical Properties of ITO Thin Films Deposited Using DC Sputtering Technique // IEEJ Transactions on Electrical and Electronic Engineering. 2018. V. 13. P. 27–31.

Supplementary files

Supplementary Files
Action
1. JATS XML
2.

Download (84KB)
3.

Download (36KB)
4.

Download (906KB)
5.

Download (1MB)
6.

Download (218KB)
7.

Download (131KB)

Copyright (c) 2023 А.В. Саенко, З.Е. Вакулов, В.С. Климин, Г.Е. Билык, С.П. Малюков

This website uses cookies

You consent to our cookies if you continue to use our website.

About Cookies