Ion-Selective Membrane Electrode for Determination of the Octahydrotriborate Anion
- Autores: Kopytin A.1, Turyshev E.1, Madraimov M.2, Kubasov A.1, Zhizhin K.1, Shpigun L.1, Kuznetsov N.1
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Afiliações:
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- Mendeleev University of Chemical Technology of Russia
- Edição: Volume 68, Nº 1 (2023)
- Páginas: 10-16
- Seção: СИНТЕЗ И СВОЙСТВА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
- URL: https://journals.rcsi.science/0044-457X/article/view/136302
- DOI: https://doi.org/10.31857/S0044457X22601432
- EDN: https://elibrary.ru/GWLWQG
- ID: 136302
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Resumo
An ion-selective electrode (ISE) based on a plasticized polyvinyl chloride membrane chemically doped with tetradecylammonium octahydrotriborate ([(С10H21)4N+]
) has been developed. It is shown that the electrode has a reversible potentiometric response with respect to the octahydrotriborate anion in the presence of a number of other inorganic anions. The influence of the concentration of the electrode-active material and the nature of the plasticizer in the membrane phase on the electrochemical characteristics of the fabricated sensor have been studied. The optimal composition of the ion-sensitive membrane has been found. It has been found that the developed sensor provides a wide range of detectable concentrations of
(1 × 10–7…1 × 10–2) and a low detection limit (10–7.3 M). The new ISE can be recommended for direct potentiometric detection of free octahydrotriborate anions in technological aqueous solutions.
Sobre autores
A. Kopytin
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: tyrishev@gmail.com
119991, Moscow, Russia
E. Turyshev
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: tyrishev@gmail.com
119991, Moscow, Russia
M. Madraimov
Mendeleev University of Chemical Technology of Russia
Email: tyrishev@gmail.com
125047, Moscow, Russia
A. Kubasov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: tyrishev@gmail.com
119991, Moscow, Russia
K. Zhizhin
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: tyrishev@gmail.com
119991, Moscow, Russia
L. Shpigun
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: tyrishev@gmail.com
119991, Moscow, Russia
N. Kuznetsov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Autor responsável pela correspondência
Email: tyrishev@gmail.com
119991, Moscow, Russia
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