Ion-Selective Membrane Electrode for Determination of the Octahydrotriborate Anion

A. V. Kopytin; Копытин А. В.; E. S. Turyshev; Турышев Е. С.; M. Sh. Madraimov; Мадраимов М. Ш.; A. S. Kubasov; Кубасов А. С.; K. Yu. Zhizhin; Жижин К. Ю.; L. K. Shpigun; Шпигун Л. К.; N. T. Kuznetsov; Кузнецов Н. Т.

doi:10.31857/S0044457X22601432

Ion-Selective Membrane Electrode for Determination of the Octahydrotriborate Anion

Authors: Kopytin A.V.¹, Turyshev E.S.¹, Madraimov M.S.², Kubasov A.S.¹, Zhizhin K.Y.¹, Shpigun L.K.¹, Kuznetsov N.T.¹
Affiliations:
1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
2. Mendeleev University of Chemical Technology of Russia
Issue: Vol 68, No 1 (2023)
Pages: 10-16
Section: СИНТЕЗ И СВОЙСТВА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
URL: https://journals.rcsi.science/0044-457X/article/view/136302
DOI: https://doi.org/10.31857/S0044457X22601432
EDN: https://elibrary.ru/GWLWQG
ID: 136302

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Abstract
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Abstract

An ion-selective electrode (ISE) based on a plasticized polyvinyl chloride membrane chemically doped with tetradecylammonium octahydrotriborate ([(С10H21)4N+]
) has been developed. It is shown that the electrode has a reversible potentiometric response with respect to the octahydrotriborate anion in the presence of a number of other inorganic anions. The influence of the concentration of the electrode-active material and the nature of the plasticizer in the membrane phase on the electrochemical characteristics of the fabricated sensor have been studied. The optimal composition of the ion-sensitive membrane has been found. It has been found that the developed sensor provides a wide range of detectable concentrations of
(1 × 10–7…1 × 10–2) and a low detection limit (10–7.3 M). The new ISE can be recommended for direct potentiometric detection of free octahydrotriborate anions in technological aqueous solutions.

Keywords

octahydrotriborate anion, polymer membrane, tetradecylammonium octahydrotriborate

References

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