Synthesis and Crystal Structures of (HL)2[B10Cl10]·3CH3CN (L = Bipy, Phen)

V. V. Avdeeva; Авдеева В. В.; A. V. Vologzhanina; Вологжанина А. В.; S. E. Nikiforova; Никифорова С. Е.; G. A. Buzanov; Бузанов Г. А.; E. A. Malinina; Малинина Е. А.; N. T. Kuznetsov; Кузнецов Н. Т.

doi:10.31857/S0044457X22602176

Synthesis and Crystal Structures of (HL)2[B10Cl10]·3CH3CN (L = Bipy, Phen)

Авторлар: Avdeeva V.¹, Vologzhanina A.², Nikiforova S.¹, Buzanov G.¹, Malinina E.¹, Kuznetsov N.¹
Мекемелер:
1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
2. A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Шығарылым: Том 68, № 6 (2023)
Беттер: 824-831
Бөлім: КООРДИНАЦИОННЫЕ СОЕДИНЕНИЯ
URL: https://journals.rcsi.science/0044-457X/article/view/136488
DOI: https://doi.org/10.31857/S0044457X22602176
EDN: https://elibrary.ru/UEPURW
ID: 136488

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Аннотация
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Әдебиет тізімі
Қосымша файлдар
Статистика

Аннотация

Reactions of (Et3NH)2[B10Cl10] and organic ligands 2,2'-bipyridyl (Bipy) and 1,10-phenanthroline (Phen) in the acetonitrile–trifluoroacetic acid system have yielded compounds of composition (HL)2[B10Cl10]·3CH3CN (L = Bipy, Phen). The compounds have been characterized by IR spectroscopy, elemental analysis, and X-ray diffraction (CCDC nos. 2224377 and 2224378). It has been shown that in the presence of trifluoroacetic acid, protonation of organic ligands occurs with the formation of bipyridylium and phenanthrolinium salts, which are stabilized by the decachloro-closo-decaborate anion. It has been found that the cations participate in the formation of hydrogen bonds with the solvate molecules of acetonitrile, while only weak C–H…Cl and B–Cl…π interactions are observed for boron cluster anions.

Негізгі сөздер

decachloro-closo-decaborate anion, bipyridyl, phenanthroline, X-ray diffraction analysis

Әдебиет тізімі

Muetterties E.L., Knoth W.H. Polyhedral Boranes. N.Y.: Dekker, 1968.
Boron Science: New Technologies and Applications / Ed. Hosmane N.S. CRC Press, 2012.
Greenwood N.N., Earnshaw A. Chemistry of the Elements. Butterworth-Heinemann, 1997.
King B.R. // Chem. Rev. 2001. V. 101. P. 1119. https://doi.org/10.1021/cr000442t
Chen Z., King R.B. // Chem. Rev. 2005. V. 105. P. 3613. https://doi.org/10.1021/cr0300892
Avdeeva V.V., Malinina E.A., Kuznetsov N.T. // Coord. Chem. Rev. 2022. V. 469. P. 214636. https://doi.org/10.1016/j.ccr.2022.214636
Авдеева В.В., Короленко С.Е., Малинина Е.А., Кузнецов Н.Т. // Журн. общей химии. 2022. Т. 92. № 3. С. 443.
Alexandrova A.N., Boldyrev A.I., Zhai H.J., Wang L.S. // Coord. Chem. Rev. 2006. V. 250. P. 2811. https://doi.org/10.1039/D2QI00890D
Zhao X., Yang Z., Chen H. et al. // Coord. Chem. Rev. 2021. V. 444. P. 214042. https://doi.org/10.1016/j.ccr.2021.214042
Сиваев И.Б. // Журн. неорган. химии. 2021. Т. 66. № 9. С. 1192. [Sivaev I.B. // Russ. J. Inorg. Chem. 2021. V. 66. P. 1289.] https://doi.org/10.1134/S0036023621090151
Nelyubin A.V., Klyukin I.N., Zhdanov A.P. et al. // Russ. J. Inorg. Chem. 2021. V. 66. P. 139. https://doi.org/10.1134/S0036023621020133
Shmal’ko A.V., Sivaev I.B. // Russ. J. Inorg. Chem. 2019. V. 64. P. 1726. https://doi.org/10.1134/S0036023619140067
Zhizhin K.Yu., Zhdanov A.P., Kuznetsov N.T. // Russ. J. Inorg. Chem. 2010. V. 55. P. 2089. https://doi.org/10.1134/S0036023610140019
Sivaev I.B., Prikaznov A.V., Naoufal D. // Collect. Czech. Chem. Commun. 2010. V. 75. P. 1149. https://doi.org/10.1135/cccc2010054
Avdeeva V.V., Buzanov G.A., Malinina E.A. et al. // Crystals. 2020. V. 10. P. 389. https://doi.org/10.3390/cryst10050389
Avdeeva V.V., Vologzhanina A.V., Ugolkova E.A. et al. // J. Solid State Chem. 2021. V. 296. P. 121989. https://doi.org/10.1016/j.jssc.2021.121989
Matveev E.Yu., Novikov I.V., Kubasov A.S. et al. // Russ. J. Inorg. Chem. 2021. V. 66. P. 187. https://doi.org/10.1134/S0036023621020121
Matveev E.Y., Avdeeva V.V., Zhizhin K.Y. et al. // Inorganics. 2022. V. 10. P. 238. https://doi.org/10.3390/inorganics10120238
Авдеева В.В., Малинина Е.А., Жижин К.Ю., Кузнецов Н.Т. // Коорд. химия. 2021. Т. 47. № 8. С. 457.
Malinina E.A., Korolenko S.E., Zhdanov A.P. et al. // J. Clust. Chem. 2021. V. 32. P. 755. https://doi.org/10.1007/s10876-020-01840-5
Сиваев И.Б. // Журн. неорган. химии. 2019. Т. 64. № 8. С. 789.
Axtell J.C., Saleh L.M.A., Qian E.A. et al. // Inorg. Chem. 2018. V. 57. № 5. P. 2333. https://doi.org/10.1021/acs.inorgchem.7b02912
Avdeeva V.V., Malinina E.A., Kuznetsov N.T. // Russ. J. Inorg. Chem. 2017. V. 62. P. 1673. https://doi.org/10.1134/S0036023617130022
Dziova A.E., Avdeeva V.V., Polyakova I.N. et al. // Dokl. Chem. 2011. V. 440. P. 253. https://doi.org/10.1134/S0012500811090035
Elrington M., Greenwood N.N., Kennedy J.D., Thornton-Pett M. // J. Chem. Soc., Dalton Trans. 1987. V. 2. P. 451. https://doi.org/10.1039/DT9870000451
Avdeeva V.V., Polyakova I.N., Churakov A.V. et al. // Polyhedron. 2019. V. 162. P. 65. https://doi.org/10.1016/j.poly.2019.01.051
Avdeeva V.V., Vologzhanina A.V., Goeva L.V. et al. // Z. Anorg. Allg. Chem. 2014. V. 640. P. 2149. https://doi.org/10.1002/zaac.201400137
Avdeeva V.V., Vologzhanina A.V., Goeva L.V. et al. // Inorg. Chim. Acta. 2015. V. 428. P. 154. https://doi.org/10.1016/j.ica.2014.12.029
Avdeeva V.V., Dziova A.E., Polyakova I.N. et al. // Polyhedron. 2015. V. 430. P. 74. https://doi.org/10.1016/j.ica.2015.02.029
Malinina E.A., Kochneva I.K., Polyakova I.N. et al. // Inorg. Chim. Acta. 2018. V. 477. P. 284. https://doi.org/10.1016/j.ica.2018.03.024
Avdeeva V.V., Vologzhanina A.V., Malinina E.A., Kuznetsov N.T. // Crystals. 2019. V. 9. P. 330. https://doi.org/10.3390/cryst9070330
Chantler C.T., Maslen E.N. // Acta Crystallogr., Sect. B. 1989. V. 45. P. 290.
Fuller D.J., Kepert D.L., Skelton B.W., White A.H. // Aust. J. Chem. 1987. V. 40. P. 2097.
Goeva L.V., Zhuchkova A.F., Malinina E.A. et al. // Russ. J. Inorg. Chem. 2022. V. 67. P. 1144. https://doi.org/10.1134/S0036023622080149
Miller H.C., Miller N.E., Muetterties E.L. // J. Am. Chem. Soc. 1963. V. 85. P. 3885.
Kravchenko E.A., Gippius A.A., Korlyukov A.A. et al. // Inorg. Chim. Acta. 2016. V. 447. P. 22. https://doi.org/10.1016/j.ica.2016.03.025
SAINT-Plus (Version 7.68) // Bruker AXS Inc., Madison, Wisconsin, USA. 2007.
SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
Sheldrick G.M. // Acta Crystallogr. 2015. V. 71A. № 1. P. 3.
Sheldrick G.M. // Acta Crystallogr. 2015. V. 71C. № 1. P. 3.
Martsinko E.E., Seifullina I.I., Chebanenko E.A. et al. // Russ. J. Coord. Chem. 2018. V. 44. P. 393. https://doi.org/10.1134/S1070328418060039
Seifullina I.I., Martsinko E.E., Chebanenko E.A. et al. // J. Struct. Chem. 2017. V. 58. P. 532. https://doi.org/10.1134/S0022476617030143
Petrosyants S.P., Ilyukhin A.B. // Russ. J. Coord. Chem. 2014. V. 40. P. 825. https://doi.org/10.1134/S107032841410008X
Yin P., Xue C., Yan Y. et al. // Russ. J. Inorg. Chem. 2022. V. 67. P. 456. https://doi.org/10.1134/S0036023622040222
Chebanenko E.A., Seifullina I.I., Martsinko E.E. et al. // Russ. J. Inorg. Chem. 2019. V. 64. P. 1132. https://doi.org/10.1134/S0036023619090043
Petrosyants S.P., Dobrokhotova Z.V., Ilyukhin A.B. et al. // Eur. J. Inorg. Chem. 2017. V. 2017. № 29. P. 3561. https://doi.org/10.1002/ejic.201700537