Thermodynamics of Cesium Molybdate-Based Single Crystals: Standard Enthalpy of Formation, Lattice Enthalpy, and Heat Capacity

N. I. Matskevich; Мацкевич Н. И.; A. N. Semerikova; Семерикова А. Н.; V. A. Trifonov; Трифонов В. А.; D. A. Samoshkin; Самошкин Д. А.; A. A. Chernov; Чернов А. А.; S. V. Stankus; Станкус С. В.; S. A. Luk’yanova; Лукьянова С. А.; V. N. Shlegel’; Шлегель В. Н.; V. P. Zaitsev; Зайцев В. П.; V. A. Kuznetsov; Кузнецов В. А.

doi:10.31857/S0044457X22601456

Thermodynamics of Cesium Molybdate-Based Single Crystals: Standard Enthalpy of Formation, Lattice Enthalpy, and Heat Capacity

Авторлар: Matskevich N.¹, Semerikova A.¹, Trifonov V.¹, Samoshkin D.¹^,2, Chernov A.², Stankus S.², Luk’yanova S.¹, Shlegel’ V.¹, Zaitsev V.¹^,3, Kuznetsov V.¹
Мекемелер:
1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
2. Kutateladze Institute of Thermophysics, Siberian Branch, Russian Academy of Sciences
3. Siberian State University of Water Transport
Шығарылым: Том 68, № 2 (2023)
Беттер: 203-208
Бөлім: ФИЗИЧЕСКИЕ МЕТОДЫ ИССЛЕДОВАНИЯ
URL: https://journals.rcsi.science/0044-457X/article/view/136455
DOI: https://doi.org/10.31857/S0044457X22601456
EDN: https://elibrary.ru/LPHEOT
ID: 136455

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат
Рұқсат жабық

Рұқсат берілді
Рұқсат жабық

Тек жазылушылар үшін

Аннотация
Авторлар туралы
Әдебиет тізімі
Қосымша файлдар
Статистика

Аннотация

Cs2MoO4 and Li1.9Cs0.1MoO4 crystals were grown from melt by the low-thermal-gradient Czochralski technique. The standard formation enthalpy of cesium molybdate Cs2MoO4 was measured by solution calorimetry. The heat capacity of Li1.9Cs0.1MoO4 was measured by differential scanning calorimetry (DSC) in the temperature range 320–710 K. The lattice enthalpy of Cs2MoO4 was calculated using the Born-Haber cycle. Cesium molybdate was shown to be thermodynamically stable to decomposition into constituent simple oxides (Cs2O and MoO3), which made it promising for application. Li1.9Cs0.1MoO4 experienced no phase transitions in the temperature range 320–710 K.

Негізгі сөздер

cesium molybdate, standard enthalpy of formation, lattice enthalpy, heat capacity, solution calorimetry, DSC calorimetry

Әдебиет тізімі

Simonenko T.L., Bocharova V.A., Simonenko N.P. et al. // Russ. J. Inorg. Chem. 2021. V. 66. P. 1779. https://doi.org/10.1134/S0036023621120160
Bekker T.B., Coron N., Danevich F.A. et al. // Astroparticle Phys. 2016. V. 72. P. 38. https://doi.org/10.1016/j.astropartphys.2015.06.002
Barinova O., Sadovskiy A., Ermochenkov I. // J. Cryst. Growth. 2017. V. 468. P. 365. https://doi.org/10.1016/j.jcrysgro.2016.10.009
Fattakhova Z.A., Vovkotrub E.G., Zhknarova G.S. // Russ. J. Inorg. Chem. 2021. V. 66. P. 35. https://doi.org/10.1134/S0036023621010022
Teng T., Xiao L., Shen L. et al. // Appl. Surf. Sci. 2022. V. 601. P. 154101. https://doi.org/10.1016/j.apsusc.2022.154101
Isaenko L.I., Korzhneva K.E., Khyzhin O.Y. et al. // J. Solid State Chem. 2019. V. 277. P. 786. https://doi.org/10.1016/j.jssc.2019.07.047
Steblevskaya N.I., Belobeletskaya M.V., Yarovaya T.P. et al. // Russ. J. Inorg. Chem. 2022. V. 67. P. 245. https://doi.org/10.1134/S0036023622020164
Kim H., Pandey I.R., Khan A. et al. // Cryst. Res. Technol. 2019. V. 54. P. 1900079. https://doi.org/10.1002/crat.201900079
Son J.K., Pandey I.R., Kim H.J. et al. // IEEE Trans. Nucl. Sci. 2018. V. 65. P. 2120. https://doi.org/10.1109/TNS.2018.2818330
Papynov E.K., Shichalin O.O., Belov A.A. et al. // Russ. J. Inorg. Chem. 2021. V. 66. P. 1434. https://doi.org/10.1134/S0036023621090114
Smith A.L., Kauric G., van Eijck L. et al. // J. Solid State Chem. 2017. V. 253. P. 89. https://doi.org/10.1016/j.jssc.2017.05.032
Matskevich N.I., Semerikova A.N., Shlegel V.N. et al. // J. Alloys Compd. 2021. V. 850. P. 156683. https://doi.org/10.1016/j.jallcom.2020.156683
Kasimkin P.V., Moskovskih V.A., Vasiliev Y.V. // J. Cryst. Growth. 2014. V. 390. P. 67. https://doi.org/10.1016/j.jcrysgro.2013.12.027
Volokitina A., Loiko P., Pavlyuk A. et al. // Opt. Mater. Express. 2020. V. 10. P. 2356. https://doi.org/10.1364/OME.400894
Matiutin A.S., Kovalenko N.A., Uspenskaya I.A. // J. Chem. Eng. Data. 2022. V. 67. P. 984. https://doi.org/10.1021/acs.jced.1c00849
Druzhinina A.I., Tiflova L.A., Monayenkova A.S. et al. // Russ. J. Phys. Chem. A. 2019. V. 93. P. 2101. https://doi.org/10.1134/S0036024419110098
Matskevich N.I., Kellerman D.G., Gelfond N.V. et al. // Russ. J. Inorg. Chem. 2020. V. 65. P. 720. https://doi.org/10.1134/S0036023620050150
Tsvetkov D.S., Sereda V.V., Malyshkin D.A. et al. // Chim. Techno Acta. 2021. V. 7. P. 42. https://doi.org/10.15826/CHIMTECH.2020.7.2.01
Matskevich N.I., Wolf Th., Vyazovkin I.V. et al. // J. Alloys Compd. 2015. V. 628. P. 126. https://doi.org/10.1016/j.jallcom.2014.11.220
Matskevich N.I., Chuprova M.V., Punn R. et al. // Thermochim. Acta. 2007. V. 459. P. 125. https://doi.org/10.1016/j.tca.2007.03.015
Matskevich N.I., Krabbes G., Berasteguie P. // Thermochim. Acta. 2003. V. 397. P. 97. https://doi.org/10.1016/S0040-6031(02)00330-1
Kilday M.V. // J. Res. Nat. Bur. Stand. 1980. V. 85. P. 467.
Gunther C., Pfestorf R., Rother M. et al. // J. Therm. Anal. Calorim. 1988. V. 33. P. 359. https://doi.org/10.1007/BF01914624
Guskov A.V., Gagarin P.G., Guskov V.N. et al. // Russ. J. Phys. Chem. A. 2022. V. 96. P. 1195. https://doi.org/10.1134/S0036024422060103
Zvereva I.A., Shelyapina M.G., Chislov M. et al. // J. Therm. Anal. Calorim. 2022. V. 147. P. 6147. https://doi.org/10.1007/s10973-021-10947-4
Kosova D.A., Provotorov D.I., Kuzovchikov S.V. et al. // Russ. J. Inorg. Chem. 2020. V. 65. P. 752. https://doi.org/10.1134/S0036023620050125
Samoshkin D.A., Agazhanov A.Sh., Stankus S.V. // J. Phys.: Conf. Ser. 2021. V. 2119. P. 012135. https://doi.org/10.1088/1742-6596/2119/1/012135
Smirnova N.N., Markin A.V., Abarbanel N.V. et al. // Russ. J. Phys. Chem. A. 2021. V. 95. P. 2387. https://doi.org/10.1134/S0036024421120219
Matskevich N.I., Wolf Th., Le Tacon M. et al. // J. Therm. Anal. Calorim. 2017. V. 130. P. 1125. https://doi.org/10.1007/s10973-017-6493-z
Drebushchak V.A., Isaenko L.I., Lobanov S.I. et al. // J. Therm. Anal. Calorim. 2017. V. 129. P. 103. https://doi.org/10.1007/s10973-017-6176-9
Tkachev E.N., Matskevich N.I., Samoshkin D.A. et al. // Phys. B: Cond. Matter. 2021. V. 612. P. 412880. https://doi.org/10.1016/j.physb.2021.412880
Khan A., Khan S., Kim H.J. et al // Optik. 2021. V. 242. P. 167035. https://doi.org/10.1016/j.ijleo.2021.167035
Glushko V.P. Termicheskie Konstanty Veshchestv (Thermal Constants of Substances), Moscow: VINITI, 1965–1982. № 1–10.
O’Hare P.A.G., Hoekstra H.R. // J. Chem. Thermodyn. 1973. V. 5. P. 851. https://doi.org/10.1016/S0021-9614(73)80047-3
Musikhin A.E., Naumov V.N., Bespyatov M.A. et al. // J. Alloys Compd. 2015. V. 639. P. 145. https://doi.org/10.1016/j.jallcom.2015.03.159
Orborne D.W., Flotov H.E., Hoekstra H.R. // J. Chem. Thermodyn. 1974. V. 6. P. 179. https://doi.org/10.1016/0021-9614(74)90260-2