Rare-Earth Nitrate Complexes with Dimethylformamide

M. I. Petrichko; Петричко М. И.; I. A. Karavaev; Караваев И. А.; E. V. Savinkina; Савинкина Е. В.; M. S. Grigoriev; Григорьев М. С.; G. A. Buzanov; Бузанов Г. А.; V. M. Retivov; Ретивов В. М.

doi:10.31857/S0044457X22601821

Rare-Earth Nitrate Complexes with Dimethylformamide

Authors: Petrichko M.I.¹, Karavaev I.A.¹, Savinkina E.V.¹, Grigoriev M.S.², Buzanov G.A.³, Retivov V.M.⁴
Affiliations:
1. Lomonosov Institute of Fine Chemical Technologies, MIREA –Russian Technological University
2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
3. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
4. National Research Center “Kurchatov Institute,”
Issue: Vol 68, No 4 (2023)
Pages: 482-491
Section: КООРДИНАЦИОННЫЕ СОЕДИНЕНИЯ
URL: https://journals.rcsi.science/0044-457X/article/view/136321
DOI: https://doi.org/10.31857/S0044457X22601821
EDN: https://elibrary.ru/FLPBBR
ID: 136321

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Abstract
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Abstract

In the rare-earth element nitrate (REE)–dimethylformamide (DMF)–water systems, which can be used to obtain nanosized REE oxides by solution combustion synthesis (SCS), the formation of coordination compounds [M(H2O)3(DMF)(NO3)3]·H2O (M = La–Pr) and [M(DMF)3(NO3)3] (M = Sm–Lu, Y) has been found. Using physicochemical methods of analysis (IR spectroscopy, X-ray powder diffraction, single-crystal X-ray diffraction, elemental analysis, thermogravimetric analysis, and differential scanning calorimetry), their composition has been determined and structural features have been established; thermolysis processes have been studied in a wide temperature range. It is shown that the final products of the decomposition of complex compounds are oxides of rare earth elements.

Keywords

lanthanides, amides, SCS method, oxides of rare earth elements

References

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