Rare-Earth Nitrate Complexes with Dimethylformamide
- Autores: Petrichko M.1, Karavaev I.1, Savinkina E.1, Grigoriev M.2, Buzanov G.3, Retivov V.4
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Afiliações:
- Lomonosov Institute of Fine Chemical Technologies, MIREA –Russian Technological University
- Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- National Research Center “Kurchatov Institute,”
- Edição: Volume 68, Nº 4 (2023)
- Páginas: 482-491
- Seção: КООРДИНАЦИОННЫЕ СОЕДИНЕНИЯ
- URL: https://journals.rcsi.science/0044-457X/article/view/136321
- DOI: https://doi.org/10.31857/S0044457X22601821
- EDN: https://elibrary.ru/FLPBBR
- ID: 136321
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Resumo
In the rare-earth element nitrate (REE)–dimethylformamide (DMF)–water systems, which can be used to obtain nanosized REE oxides by solution combustion synthesis (SCS), the formation of coordination compounds [M(H2O)3(DMF)(NO3)3]·H2O (M = La–Pr) and [M(DMF)3(NO3)3] (M = Sm–Lu, Y) has been found. Using physicochemical methods of analysis (IR spectroscopy, X-ray powder diffraction, single-crystal X-ray diffraction, elemental analysis, thermogravimetric analysis, and differential scanning calorimetry), their composition has been determined and structural features have been established; thermolysis processes have been studied in a wide temperature range. It is shown that the final products of the decomposition of complex compounds are oxides of rare earth elements.
Palavras-chave
Sobre autores
M. Petrichko
Lomonosov Institute of Fine Chemical Technologies, MIREA –Russian Technological University
Email: savinkina@mirea.ru
119571, Moscow, Russia
I. Karavaev
Lomonosov Institute of Fine Chemical Technologies, MIREA –Russian Technological University
Email: savinkina@mirea.ru
119571, Moscow, Russia
E. Savinkina
Lomonosov Institute of Fine Chemical Technologies, MIREA –Russian Technological University
Email: savinkina@mirea.ru
119571, Moscow, Russia
M. Grigoriev
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: savinkina@mirea.ru
119071, Moscow, Russia
G. Buzanov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: savinkina@mirea.ru
119991, Moscow, Russia
V. Retivov
National Research Center “Kurchatov Institute,”
Autor responsável pela correspondência
Email: savinkina@mirea.ru
123182, Moscow, Russia
Bibliografia
- Concise Encyclopedia of Self-Propagating High-Temperature Synthesis / Eds. Borovinskaya I.P., Gromov A.A., Levashov E.A. et al. Amsterdam: Elsevier, 2017.
- Varma A., Mukasyan A.S., Rogachev A.S., Manu-kyan K.V. // Chem. Rev. 2016. V. 116. № 23. P. 14493. https://doi.org/10.1021/acs.chemrev.6b00279
- Mukasyan A.S., Epstein P., Dinka P. // Proc. Combust. Inst. 2007. V. 31. № 2. P. 1789. https://doi.org/10.1016/j.proci.2006.07.052
- Ghosh S.K., Patra S.N., Roy S.K. et al. // Ratio. 2008. V. 1. № 2. P. 130.
- Kumar A., Wolf E.E., Mukasyan A.S. // Alche J. 2011. V. 57. № 12. P. 3473. https://doi.org/10.1002/aic.12537
- Christy A.J., Umadevi M. // Mater. Res. Bull. 2013. V. 48. № 10. P. 4248. https://doi.org/10.1016/j.materresbull.2013.06.072
- Cross A., Roslyakov S., Manukyan K.V. et al. // J. Phys. Chem. 2014. V. 118. № 45. P. 26191. https://doi.org/10.1021/jp508546n
- Khaliullin Sh.M., Zhuravlev V.D., Russkikh O.V. et al. // Int. J. Self-Propag. High-Temp. Synth. 2015. V. 24. № 2. P. 83. https://doi.org/10.3103/S106138621502003X
- Zhu Z., Zhang Y., Zhang Y. et al. // Materials. 2019. V. 12. № 6. P. 896. https://doi.org/10.3390/ma12060896
- Sahu R.K., Ray A.K., Das S.K. et al. // J. Mater. Res. 2006. V. 21. № 7. P. 1664. https://doi.org/10.1557/jmr.2006.0211
- Savinkina E.V., Karavaev I.A., Grigoriev M.S. et al. // Inorg. Chim. Acta. 2022. V. 532. P. 120759. https://doi.org/10.1016/j.ica.2021.120759
- Abu-Zied B.M. // Appl. Surf. Sci. 2019. V. 471. P. 246. https://doi.org/10.1016/j.apsusc.2018.12.007
- Kingsley J.J., Manickam N., Patil K.C. // Bull. Mater. Sci. 1990. V. 13. № 3. P. 179. https://doi.org/10.1007/BF02744944
- Pathan A.A., Desai K.R., Vajapara S., Bhasin C.P. // Adv. Nanopart. 2018. V. 7. № 1. P. 28. https://doi.org/10.4236/anp.2018.71003
- Pathan A.A., Desai K.R., Bhasin C. // Int. J. Nano. Chem. 2017. V. 3. P. 21. https://doi.org/10.18576/ijnc/030201
- Deshpande K., Mukasyan A., Varma A. // Chem. Mater. 2004. V. 16. № 16. P. 4896. https://doi.org/10.1021/cm040061m
- Bai J., Meng F., Wei C. et al. // Ceram. Silik. 2011. V. 55. № 1. P. 20.
- Mukasyan A.S., Dinka P. // Int. J. Self-Propag. High-Temp. Synth. 2007. V. 16. № 1. P. 23. https://doi.org/10.3103/S1061386207010049
- Voskanyan A.A., Chan K.Y. // J. Exp. Nanosci. 2015. V. 6. № 6. P. 466. https://doi.org/10.1080/17458080.2013.843028
- Krishnamurthy S.S., Soundararajan S. // J. Inorg. Nucl. Chem. 1966. V. 28. № 8. P. 1689. https://doi.org/10.1016/0022-1902(66)80071-4
- Dao C.N., Rudert R., Luger P. et al. // Acta Crystallogr. 1992. V. C48. № 8. P. 449. https://doi.org/10.1107/S0108270191009939
- Krishnamurthy S.S., Soundararajan S. // Can. J. Chem. 1969. V. 47. № 6. P. 995. https://doi.org/10.1139/v69-157
- Hoch C. // Z. Kristallogr. Cryst. Mater. 2020. V. 235. № 8–9. P. 401. https://doi.org/10.1515/zkri-2020-0071
- Sheldrick G.M. SADABS. Madison, Wisconsin (USA): Bruker AXS, 2008.
- Sheldrick G.M. // Acta Crystallogr., Sect. A. 2008. V. 64. № 1. P. 112. https://doi.org/10.1107/S0108767307043930
- Sheldrick G.M. // Acta Crystallogr., Sect. C. 2015. V. 714. № 1. P. 3. https://doi.org/10.1107/S2053229614024218
- Накамото К. // ИК-спектры и спектры КР неорганических и координационных соединений. М.: Мир, 1991. 536 с.
- Hay B.P., Hancock R.D. // Coord. Chem. Rev. 2001. V. 21. № 1. P. 61. https://doi.org/10.1016/S0010-8545(00)00366-0
- Hay B.P., Clement O., Sandrone G., Dixon D.A. // Inorg. Chem. 1998. V. 37. № 22. P. 5887. https://doi.org/10.1021/ic980641j
- Hansen P.E. // Molecules. 2021. V. 26. № 9. P. 2409. https://doi.org/10.3390/molecules26092409
- Shi X., Bao W. // Front. Chem. 2021. V. 9. P. 723718. https://doi.org/10.3389/fchem.2021.723718
- Рукк Н.С., Шамсиев Р.С., Альбов Д.В., Мудрецова С.Н. // Тонкие химические технологии. 2021. Т. 16. № 2. С. 113. https://doi.org/10.32362/2410-6593-2021-16-2-113-124
- Savinkina E.V., Karavaev I.A., Grigoriev M.S. // Polyhedron. 2020. V. 192. P. 114875. https://doi.org/10.1016/j.poly.2020.114875
- Караваев И.А., Савинкина Е.В., Григорьев М.С. и др. // Журн. неорган. химии. 2022. Т. 67. № 8. С. 1080.