电邮这篇文章 Materials based on carbon-filled porous layers of PVC cyclam derivatives cross-linked with the surfaces of asbestos fabric fibers
- 作者: Tzivadze A.Y.1, Fridman A.Y.1, Morozova E.M.1, Sokolova N.P.1, Voloshchuk A.M.1, Petukhova G.A.1, Bardishev I.I.1, Gorbunov A.M.1, Novikov A.K.1, Polyakova I.Y.1, Titova V.N.1, Yavich A.A.1, Petrova N.V.1
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隶属关系:
- Frumkin Institute of Physical Chemistry and Electrochemistry
- 期: 卷 90, 编号 8 (2016)
- 页面: 1644-1649
- 栏目: Physical Chemistry of Surface Phenomena
- URL: https://journals.rcsi.science/0036-0244/article/view/168627
- DOI: https://doi.org/10.1134/S0036024416080306
- ID: 168627
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详细
The synthesis of bilayer materials with porous upper layers composed of PVC hydroxyethylcyclam derivatives filled with carbon and a layer consisting of hydroxyethylcyclam, cross-linked via Si–O–C groups with the silica chains of a developed surface of asbestos fabric, is described. The aza-crown groups in these materials are bound with aqua complexes of H2SO4 or NaOH. The structure of the materials is examined, their adsorption characteristics are determined, and the rate of motion of H+ or OH– ions in electrochemical bridges is measured, while the formation of H2 and O2 in their cathodic and anodic polarization is determined as a function of voltage. It is shown that the upper layer of these materials is adsorption-active and electronand H+- or OH–- conductive, while the bottom layer is only H+- or OH–- conductive; through it, the upper layer is supplied with the H+ or OH– ions needed for the regeneration of the aqua complexes broken down to H2 and O2 on carbon particles.
作者简介
A. Tzivadze
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071
A. Fridman
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071
E. Morozova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071
N. Sokolova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071
A. Voloshchuk
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071
G. Petukhova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071
I. Bardishev
Frumkin Institute of Physical Chemistry and Electrochemistry
编辑信件的主要联系方式.
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071
A. Gorbunov
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071
A. Novikov
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071
I. Polyakova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071
V. Titova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071
A. Yavich
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071
N. Petrova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071
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