Email this article Materials based on carbon-filled porous layers of PVC cyclam derivatives cross-linked with the surfaces of asbestos fabric fibers
- Authors: Tzivadze A.Y.1, Fridman A.Y.1, Morozova E.M.1, Sokolova N.P.1, Voloshchuk A.M.1, Petukhova G.A.1, Bardishev I.I.1, Gorbunov A.M.1, Novikov A.K.1, Polyakova I.Y.1, Titova V.N.1, Yavich A.A.1, Petrova N.V.1
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Affiliations:
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Issue: Vol 90, No 8 (2016)
- Pages: 1644-1649
- Section: Physical Chemistry of Surface Phenomena
- URL: https://journals.rcsi.science/0036-0244/article/view/168627
- DOI: https://doi.org/10.1134/S0036024416080306
- ID: 168627
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Abstract
The synthesis of bilayer materials with porous upper layers composed of PVC hydroxyethylcyclam derivatives filled with carbon and a layer consisting of hydroxyethylcyclam, cross-linked via Si–O–C groups with the silica chains of a developed surface of asbestos fabric, is described. The aza-crown groups in these materials are bound with aqua complexes of H2SO4 or NaOH. The structure of the materials is examined, their adsorption characteristics are determined, and the rate of motion of H+ or OH– ions in electrochemical bridges is measured, while the formation of H2 and O2 in their cathodic and anodic polarization is determined as a function of voltage. It is shown that the upper layer of these materials is adsorption-active and electronand H+- or OH–- conductive, while the bottom layer is only H+- or OH–- conductive; through it, the upper layer is supplied with the H+ or OH– ions needed for the regeneration of the aqua complexes broken down to H2 and O2 on carbon particles.
About the authors
A. Yu. Tzivadze
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Russian Federation, Moscow, 119071
A. Ya. Fridman
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Russian Federation, Moscow, 119071
E. M. Morozova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Russian Federation, Moscow, 119071
N. P. Sokolova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Russian Federation, Moscow, 119071
A. M. Voloshchuk
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Russian Federation, Moscow, 119071
G. A. Petukhova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Russian Federation, Moscow, 119071
I. I. Bardishev
Frumkin Institute of Physical Chemistry and Electrochemistry
Author for correspondence.
Email: bardyshev@phyche.ac.ru
Russian Federation, Moscow, 119071
A. M. Gorbunov
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Russian Federation, Moscow, 119071
A. K. Novikov
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Russian Federation, Moscow, 119071
I. Ya. Polyakova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Russian Federation, Moscow, 119071
V. N. Titova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Russian Federation, Moscow, 119071
A. A. Yavich
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Russian Federation, Moscow, 119071
N. V. Petrova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Russian Federation, Moscow, 119071
