Мақаланы E-mail арқылы жіберу Layers of cyclam-substituted PVC with sodium hydroxide aqua complexes with aza-crown ligands on cellulose tissue filled with active coal
- Авторлар: Fridman A.1, Tsivadze A.1, Morozova E.1, Sokolova N.1, Voloshchuk A.1, Petukhova G.1, Bardyshev I.1, Gorbunov A.1, Novikov A.1, Polyakova I.1, Titova V.1, Yavich A.1, Petrova N.1
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Мекемелер:
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Шығарылым: Том 90, № 3 (2016)
- Беттер: 641-646
- Бөлім: Physical Chemistry of Surface Phenomena
- URL: https://journals.rcsi.science/0036-0244/article/view/167929
- DOI: https://doi.org/10.1134/S0036024416030109
- ID: 167929
Дәйексөз келтіру
Ашық рұқсат
Рұқсат берілді
Тек жазылушылар үшін
Аннотация
A material with an electrically ОН–-conductive porous layer of cyclam-substituted PVC filled with active coal containing NaOH aqua complexes with aza-crown ligands and cross-linked with the surface of cellulose tissue fibers has been synthesized. The structure of the material was studied. Its sorption capacity in vapors and liquid benzene and hexane, specific resistance, potential of ОН- transfer from solution to layer, and rate constants of ОН– travel in the layer of the material as an electrochemical bridge in vapors and liquid benzene and hexane were determined. The aqua complexes decomposed in the layer with formation of Н2 during the cathodic polarization of the bridge and О2 during the anodic polarization; the composition of the complexes was regenerated due to the motion of ОН–.
Негізгі сөздер
Авторлар туралы
A. Fridman
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Ресей, Moscow
A. Tsivadze
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Ресей, Moscow
E. Morozova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Ресей, Moscow
N. Sokolova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Ресей, Moscow
A. Voloshchuk
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Ресей, Moscow
G. Petukhova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Ресей, Moscow
I. Bardyshev
Frumkin Institute of Physical Chemistry and Electrochemistry
Хат алмасуға жауапты Автор.
Email: bardyshev@phyche.ac.ru
Ресей, Moscow
A. Gorbunov
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Ресей, Moscow
A. Novikov
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Ресей, Moscow
I. Polyakova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Ресей, Moscow
V. Titova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Ресей, Moscow
A. Yavich
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Ресей, Moscow
N. Petrova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Ресей, Moscow
