Отправить статью по E-mail Layers of cyclam-substituted PVC with sodium hydroxide aqua complexes with aza-crown ligands on cellulose tissue filled with active coal
- Авторы: Fridman A.1, Tsivadze A.1, Morozova E.1, Sokolova N.1, Voloshchuk A.1, Petukhova G.1, Bardyshev I.1, Gorbunov A.1, Novikov A.1, Polyakova I.1, Titova V.1, Yavich A.1, Petrova N.1
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Учреждения:
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Выпуск: Том 90, № 3 (2016)
- Страницы: 641-646
- Раздел: Physical Chemistry of Surface Phenomena
- URL: https://journals.rcsi.science/0036-0244/article/view/167929
- DOI: https://doi.org/10.1134/S0036024416030109
- ID: 167929
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Аннотация
A material with an electrically ОН–-conductive porous layer of cyclam-substituted PVC filled with active coal containing NaOH aqua complexes with aza-crown ligands and cross-linked with the surface of cellulose tissue fibers has been synthesized. The structure of the material was studied. Its sorption capacity in vapors and liquid benzene and hexane, specific resistance, potential of ОН- transfer from solution to layer, and rate constants of ОН– travel in the layer of the material as an electrochemical bridge in vapors and liquid benzene and hexane were determined. The aqua complexes decomposed in the layer with formation of Н2 during the cathodic polarization of the bridge and О2 during the anodic polarization; the composition of the complexes was regenerated due to the motion of ОН–.
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Об авторах
A. Fridman
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow
A. Tsivadze
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow
E. Morozova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow
N. Sokolova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow
A. Voloshchuk
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow
G. Petukhova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow
I. Bardyshev
Frumkin Institute of Physical Chemistry and Electrochemistry
Автор, ответственный за переписку.
Email: bardyshev@phyche.ac.ru
Россия, Moscow
A. Gorbunov
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow
A. Novikov
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow
I. Polyakova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow
V. Titova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow
A. Yavich
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow
N. Petrova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow
