Email this article Layers of cyclam-substituted PVC with sodium hydroxide aqua complexes with aza-crown ligands on cellulose tissue filled with active coal
- Authors: Fridman A.Y.1, Tsivadze A.Y.1, Morozova E.M.1, Sokolova N.P.1, Voloshchuk A.M.1, Petukhova G.A.1, Bardyshev I.I.1, Gorbunov A.M.1, Novikov A.K.1, Polyakova I.Y.1, Titova V.N.1, Yavich A.A.1, Petrova N.V.1
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Affiliations:
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Issue: Vol 90, No 3 (2016)
- Pages: 641-646
- Section: Physical Chemistry of Surface Phenomena
- URL: https://journals.rcsi.science/0036-0244/article/view/167929
- DOI: https://doi.org/10.1134/S0036024416030109
- ID: 167929
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Abstract
A material with an electrically ОН–-conductive porous layer of cyclam-substituted PVC filled with active coal containing NaOH aqua complexes with aza-crown ligands and cross-linked with the surface of cellulose tissue fibers has been synthesized. The structure of the material was studied. Its sorption capacity in vapors and liquid benzene and hexane, specific resistance, potential of ОН- transfer from solution to layer, and rate constants of ОН– travel in the layer of the material as an electrochemical bridge in vapors and liquid benzene and hexane were determined. The aqua complexes decomposed in the layer with formation of Н2 during the cathodic polarization of the bridge and О2 during the anodic polarization; the composition of the complexes was regenerated due to the motion of ОН–.
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About the authors
A. Ya. Fridman
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Russian Federation, Moscow
A. Yu. Tsivadze
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Russian Federation, Moscow
E. M. Morozova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Russian Federation, Moscow
N. P. Sokolova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Russian Federation, Moscow
A. M. Voloshchuk
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Russian Federation, Moscow
G. A. Petukhova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Russian Federation, Moscow
I. I. Bardyshev
Frumkin Institute of Physical Chemistry and Electrochemistry
Author for correspondence.
Email: bardyshev@phyche.ac.ru
Russian Federation, Moscow
A. M. Gorbunov
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Russian Federation, Moscow
A. K. Novikov
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Russian Federation, Moscow
I. Ya. Polyakova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Russian Federation, Moscow
V. N. Titova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Russian Federation, Moscow
A. A. Yavich
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Russian Federation, Moscow
N. V. Petrova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Russian Federation, Moscow
