电邮这篇文章 Layers of cyclam-substituted PVC with sodium hydroxide aqua complexes with aza-crown ligands on cellulose tissue filled with active coal
- 作者: Fridman A.1, Tsivadze A.1, Morozova E.1, Sokolova N.1, Voloshchuk A.1, Petukhova G.1, Bardyshev I.1, Gorbunov A.1, Novikov A.1, Polyakova I.1, Titova V.1, Yavich A.1, Petrova N.1
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隶属关系:
- Frumkin Institute of Physical Chemistry and Electrochemistry
- 期: 卷 90, 编号 3 (2016)
- 页面: 641-646
- 栏目: Physical Chemistry of Surface Phenomena
- URL: https://journals.rcsi.science/0036-0244/article/view/167929
- DOI: https://doi.org/10.1134/S0036024416030109
- ID: 167929
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详细
A material with an electrically ОН–-conductive porous layer of cyclam-substituted PVC filled with active coal containing NaOH aqua complexes with aza-crown ligands and cross-linked with the surface of cellulose tissue fibers has been synthesized. The structure of the material was studied. Its sorption capacity in vapors and liquid benzene and hexane, specific resistance, potential of ОН- transfer from solution to layer, and rate constants of ОН– travel in the layer of the material as an electrochemical bridge in vapors and liquid benzene and hexane were determined. The aqua complexes decomposed in the layer with formation of Н2 during the cathodic polarization of the bridge and О2 during the anodic polarization; the composition of the complexes was regenerated due to the motion of ОН–.
作者简介
A. Fridman
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow
A. Tsivadze
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow
E. Morozova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow
N. Sokolova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow
A. Voloshchuk
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow
G. Petukhova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow
I. Bardyshev
Frumkin Institute of Physical Chemistry and Electrochemistry
编辑信件的主要联系方式.
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow
A. Gorbunov
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow
A. Novikov
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow
I. Polyakova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow
V. Titova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow
A. Yavich
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow
N. Petrova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow
