Radiolytic modification of polymer filler for cement compositions
- Authors: Kholodkova E.M.1, Nevolin Y.M.1, Shapagin A.V.2, Grafov O.Y.1, Ponomarev A.V.1
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Affiliations:
- A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
- A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences Leninsky prospekt 31(4), Moscow, 119071 Russia
- Issue: Vol 58, No 1 (2024)
- Pages: 54-59
- Section: РАДИАЦИОННАЯ ХИМИЯ
- URL: https://journals.rcsi.science/0023-1193/article/view/258148
- DOI: https://doi.org/10.31857/S0023119324010055
- EDN: https://elibrary.ru/KAHFSP
- ID: 258148
Cite item
Abstract
The influence of preliminary irradiation (3 MeV electron beam) of powdered (≤0.2 mm) synthetic polymers (polyethylene, polypropylene, polyvinyl chloride, polycarbonate, polyethylene terephthalate, or polystyrene) on the compressive strength of cement-sand-polymer compositions has been studied. The surface oxidation of the powders was ensured by irradiation in air or in a water-air mixture. It is shown that the oxidation of the powder in an aqueous medium, as well as the post-radiation alkalization of the powders, contribute to a higher strength of the composites. Oxidation of the powder in air leads to a relative decrease in the strength of the composite due to a higher yield of acid formation.
Keywords
Full Text
About the authors
E. M. Kholodkova
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
Email: ponomarev@ipc.rssi.ru
Russian Federation, Leninsky prospekt 31(4), Moscow, 119071
Yu. M. Nevolin
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
Email: ponomarev@ipc.rssi.ru
Russian Federation, Leninsky prospekt 31(4), Moscow, 119071
A. V. Shapagin
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of SciencesLeninsky prospekt 31(4), Moscow, 119071 Russia
Email: ponomarev@ipc.rssi.ru
Russian Federation, A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
Leninsky prospekt 31(4), Moscow, 119071
O. Yu. Grafov
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
Email: ponomarev@ipc.rssi.ru
Russian Federation, Leninsky prospekt 31(4), Moscow, 119071
A. V. Ponomarev
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
Author for correspondence.
Email: ponomarev@ipc.rssi.ru
Russian Federation, Leninsky prospekt 31(4), Moscow, 119071
References
- Sandanayake M., Bouras Y., Haigh R., Vrcelj Z. // Sustainability, 2020, V. 12. P. 9622. https://doi.org/10.3390/su12229622
- Gu L., Ozbakkaloglu T. // Waste Manag. 2016. V. 51. Р. 19. https://doi.org/10.1016/j.wasman.2016.03.005
- Abu-Saleem M., Zhuge Y., Hassanli R., Ellis M., Rahman M.M., Levett P. // Case Stud. Constr. Mater. 2021. V. 15. Р. e00728. https://doi.org/10.1016/j.cscm.2021.e00728
- Cheon H., Ruziev J., Lee H., Kang Y., Roh S., Kim W. // Appl. Sci. 2021. V. 11. Р. 11982. https://doi.org/ 10.3390/app112411982
- Ponomarev A.V. // High Energy Chem. 2020. V. 54. Р. 194. https://doi.org/10.1134/S0018143920030121
- Ponomarev A.V., Gohs U., Ratnam C., Horak C. // Radiat. Phys. Chem. 2022. V. 201. Р. 110397. https://doi.org/10.1016/j.radphyschem.2022.110397
- Lee H., Cheon H., Kang Y., Roh S., Kim W. // Appl. Sci. 2021. V. 11. Р. 10340. https://doi.org/10.3390/app112110340
- Woods R., Pikaev A. // Applied Radiation Chemistry. Radiation Processing. New York: Wiley, 1994.
- Khusyainova D.N., Shapagin A.V., Ponomarev A.V. // Radiat. Phys. Chem. 2022. V. 192. Р. 109918. https://doi.org/10.1016/j.radphyschem.2021.109918
- Bludenko A.V., Ponomarev A.V., Kholodkova E.M., Khusyainova D.N., Shapagin A.V. // High Energy Chem. 2022. V. 56. Р. 258. https://doi.org/10.1134/S0018143922040130
- Vcherashnyaya A.S., Mikhailova M.V., Shapagin A.V., Poteryaev A.A., Stepanenko V.Y., Ponomarev A.V. // High Energy Chem. 2021. V. 55. Р. 295. https://doi.org/10.1134/S0018143921040159
- Kholodkova E.M., Shapagin A.V., Ponomarev A.V. // High Energy Chem. 2022. V. 56. Р. 383. https://doi.org/10.1134/S001814392205006X
- Shirley D.A. // Phys. Rev. B. 1972. V. 5. Р. 4709. https://doi.org/10.1103/PhysRevB.5.4709
- Scofield J.H. // J. Electron Spectros. Relat. Phenomena. 1976. V. 8. Р. 129. https://doi.org/10.1016/0368-2048(76)80015-1
- Zaikov G.E., Rakovsky S.K. // Ozonation of Organic and Polymer Compounds. Smithers Rapra Technology, 2009.
- Orzechowska G.E., Nguyen H.T., Paulson S.E. // J. Phys. Chem. A. 2005. V. 109. Р. 5366. https://doi.org/ 10.1021/jp050167k
- Bertron A., Duchesne J., Escadeillas G. // Cem. Concr. Res. 2005. V. 35. Р. 155. https://doi.org/10.1016/j.cemconres.2004.09.009
- Oueslati O., Duchesne J. // Cem. Concr. Compos. 2014. V. 45. Р. 89. https://doi.org/10.1016/j.cemconcomp. 2013.09.007
- Paine K.A. Elsevier. 2019. Р. 285–339. https://doi.org/10.1016/B978-0-08-100773-0.00007-1
- Marchon D., Flat R.J. // Mechanisms of cement hydration, in: Science and Technology of Concrete Admixtures. Elsevier. 2016. Р. 129. https://doi.org/10.1016/B978-0-08-100693-1.00008-4