Synthesis and characterization of the MIIU3O10 · 6H2O (MII = Ni, Zn) triuranates


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We have developed a process for the synthesis of Ni(II) and Zn(II) triuranates with the general formula MIIU3O10 · 6H2O through reaction of schoepite, UO3 · 2.25H2O, with aqueous solutions of nickel and zinc nitrates under hydrothermal conditions. Using chemical analysis, X-ray diffraction, IR spectroscopy, and thermal analysis, we have determined the composition and structure of the triuranates and investigated their dehydration and thermal decomposition.

Sobre autores

O. Nipruk

Lobachevsky State University

Autor responsável pela correspondência
Email: nipruk@yandex.ru
Rússia, pr. Gagarina 23, Nizhny Novgorod, 603950

N. Chernorukov

Lobachevsky State University

Email: nipruk@yandex.ru
Rússia, pr. Gagarina 23, Nizhny Novgorod, 603950

K. Chaplieva

Lobachevsky State University

Email: nipruk@yandex.ru
Rússia, pr. Gagarina 23, Nizhny Novgorod, 603950

G. Chernorukov

Lobachevsky State University

Email: nipruk@yandex.ru
Rússia, pr. Gagarina 23, Nizhny Novgorod, 603950

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