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Vol 55, No 15 (2019)

Structure and Properties Research Physical Methods of Research and Monitoring

Directional Crystallization of 316L Stainless Steel Specimens by Direct Laser Deposition

Gorunov A.I.

Abstract

Advantages of direct laser deposition of metal providing the directional crystallization of 316L stainless steel specimens are shown. It is found that direct laser deposition of metal offers exciting possibilities for obtaining monocrystalline structures by directional crystallization of the deposited metal. The metal structure of the obtained specimens is represented by dendritic crystals oriented toward the thermal center. The cross-section view of the structure, formed by the crystal axes of the first order, is of the form of honeycombs. The thickness of the applied layer (200 µm) in the central part of the specimen does not prevent the development of the dendrite structure and it contributes to the formation of the monocrystalline structures (having no pores and cracks). It was stated that the growth orientation of dendritic crystals is driven by the thermal center determined by the position of the laser spot. A technique of manufacturing stainless steel products by direct laser deposition using the developed algorithm which allowed connecting the movement of the robotic center and specimen, laser switching, and feeding of the gas-powder mixture was presented. The possibilities of estimating the inclination angle of dendritic crystals in the metal relative to the symmetry axis of the specimen using a metallographic software package for analysis of digital images of the microstructures, as well as the quality control of the items obtained by the X-ray tomographic quality control, determination of the parameters of the laser spot on the substrate surface using high-speed photography, and estimation of the phase composition of the deposited metal using X-ray diffraction analysis, are shown. In such a case, the roughness of the specimens determined by the size of the powder particles may be removed by mechanical treatment.

Inorganic Materials. 2019;55(15):1439-1444
pages 1439-1444 views

Thermographic Control by New Methods of Multiscale Analysis of Nonstationary Thermal Fields

Golovin Y.I., Tyurin A.I., Golovin D.Y., Samodurov A.A.

Abstract

In this paper, we present the results of the application of new methods of monitoring and diagnostics based on a computer analysis of multiscale dynamic thermographic patterns. Depending on the size of the inspected area, as well as the nature, location, orientation, and size of defects, various energy sources, such as an airflow, focused laser beam, and point contact, were used for probing dynamic heating of the product under control. The nonstationary thermal image of the monitored area was recorded by a high-resolution thermal camera and then analyzed by using original model approaches and developed specialized software. The development of defects was initiated by a calibrated local power load using the built-in force generator. This allowed identifying dynamic (prone-to-growth) defects and assessing the degree of their danger for further operation and the residual resource of the product. Using the proposed methods, defects of various types (cracks, delaminations, detachments, and degradation of coatings, defects in welding and adhesive joints, deposits of transported substances, etc.), sizes (from fractions to tens of millimeters), and location in the product (near both the outer and inner surfaces of vessels, pipelines, reactors, tanks, etc.) can be detected and quantitatively characterized. The developed techniques also allow determining the thermophysical characteristics of the material, in particular, the thermal diffusivity coefficient with an accuracy better than ±3%.

Inorganic Materials. 2019;55(15):1445-1453
pages 1445-1453 views

Acoustic Measurement of the Texture Characteristics of 15YuTA Construction Steel under Fatigue Failure

Mishakin V.V., Serebryany V.N., Gonchar A.V., Klyushnikov V.A.

Abstract

This paper presents results from studies on the change in the texture and Poisson coefficients of 15YuTA construction steel upon fatigue failure in the range of high-cycle fatigue by the ultrasonic pulse-echo technique. The coefficients of the orientation distribution functions (\(W_{4}^{{00}}\) and \(W_{4}^{{20}}\)) used for construction of the pole figures were obtained using bulk elastic waves and the precise measurement of its propagation time. As a parameter characterizing the texture sharpness, the intensity ratio in the center of the pole figure and at a point remote from the center by 45° along the rolling direction was used. It was shown that change in the texture sharpness is attributed to the development of microplastic strain and accumulation of microdefects. A nonmonotonic dependence of the change in the sharpness of the texture on the number of loading cycles is observed. At the initial (first) stage of loading, there is some increase in the sharpness, which can be attributed to the development of microstrains on the most favorably oriented sliding planes. At the second stage, the decrease in the sharpness is associated with the scattering of the texture upon the increase in the density of microdefects during the destruction of the alloy. The parameter characterizing the sharpness of the texture can be used as a pre-destruction indicator by the ultrasonic monitoring of a construction material.

Inorganic Materials. 2019;55(15):1454-1457
pages 1454-1457 views

Study of Properties of Materials by Absorption and Diffraction X-Ray Microtomography

Asadchikov V.E., Buzmakov A.V., Dyachkova I.G., Zolotov D.A., Krivonosov Y.S., Rusakov A.A., Chukhovskii F.N.

Abstract

Single crystals of silicon and gallstones are studied on a laboratory X-ray microtomograph with a spatial resolution of 10 μm. The tomographic experiment included the use of a monochromatic “parallel beam” with subsequent three-dimensional reconstruction based on two-dimensional projections. The topo-tomographic measurements were performed in the rotation mode of the samples around the normal to the reflection plane tuned by the Laue diffraction reflection geometry, which allowed identification and study of single dislocations in perfect silicon crystals. The dislocation loops were simulated by means of a numerical solution of the Takagi–Taupin equations. Human gallstones were studied in vitro with microtomography. We found that the stones have a layered formation, whose composition may involve calcium carbonate modifications. The internal structure of the stones is heterogeneous and contains numerous cavities and cracks formed during their growth. The assessment of the porosity of gallstones, however, is necessary, because it can affect the dissolution rate of the stone during litholytic treatment. Linear attenuation coefficients of X‑ray radiation of cholesterol-type gallstones were found from the results of measurements. A good agreement between the experimental and calculated absorption coefficients for pure cholesterol suggests that the tomographic method can be used for in vivo diagnosis of cholesterol-type gallstones.

Inorganic Materials. 2019;55(15):1458-1464
pages 1458-1464 views

Mechanics of Materials: Strength, Durability, Safety

Integrated Mechanical Strength Tests of the Main Pipeline for Transporting Crude Oil and Refined Products

Lisin Y.V., Makhutov N.A., Neganov D.A., Studenov E.P., Skorodumov S.V.

Abstract

The state, problems, and prospects of conventional, unified and special laboratory, bench and full-scale tests to substantiate the systematic assessment of strength, durability, survivability, cold resistance, reliability, and safety of the key elements of pipeline transport of crude oil and refined products are considered. These tests correlate with the stages of the pipeline life cycles and basic and reference computational-experimental methods of determining the criterial characteristics of pipe steels, pipes and main pipelines with regard to domestic and foreign practices. The experimental basic mechanical characteristics obtained in standard static tensile tests (yield and strength limits, elastic moduli) are part of the basic static strength calculations of newly designed and operating pipelines. Standard hardness and impact elasticity tests are used to control the pipe steel quality. The results of standard tensile tests provide additional design information for the assessment of static strength with respect to the ductility and degree of steel hardening during elastoplastic deformation. Unified laboratory tests are meant for refining the pipeline strength with allowance for the stress state 3D effects, absolute sizes of the pipeline cross section, strain rate, anisotropy, cold resistance, corrosion, and the presence of welded joints. The assessment of pipe steel crack resistance and pipes according to the criteria of linear and nonlinear fracture mechanics with allowance for technological and operational defects holds a specific place in laboratory and bench testing. The experience in conducting these tests, accumulated in the Russian oil pipeline system is considered.

Inorganic Materials. 2019;55(15):1465-1475
pages 1465-1475 views

Experimental Study of Crack Branching Velocity in Polymers

Alexeev A.A., Bolshev K.N., Ivanov V.A., Syromyatnikova A.S., Bolshakov A.M., Andreev A.S.

Abstract

One of the little-studied problems of modern mechanics and the physics of destruction is crack branching, which is observed in materials of varying nature. In order to study this phenomenon, the criteria and mechanisms for crack branching are analyzed. Studies of crack branching in polymers and steel, as well as fractographic studies of the fracture surface, are considered. It is found that the crack at branching in brittle plastics reaches the limiting propagation velocity V* = 500–800 m/s. Tensile tests of flat samples made of polymethyl methacrylate (PMMA) at temperatures of +20 and –60°C are carried out with measurement of crack velocity by the method of rupture of conductive strips. A measuring device based on a TERCON precision converter of signals of resistance thermometers and thermocouples connected to a computer is created. Crack velocity is measured for (i) rectilinear crack propagation in the mirror, matte, and feather zones of PMMA fracture surface, (ii) single branching of the crack, and (iii) multiple crack branching with parallel movement of the front of several cracks. A hypothesis for the physical mechanism of crack branching is proposed.

Inorganic Materials. 2019;55(15):1476-1480
pages 1476-1480 views

Fracturing Behavior of Metalware Made of 30KhGSA Steel

Grigorenko V.B., Morozova L.V.

Abstract

The reasons for fracture of fasteners made of 30KhGSA steel were analyzed. It was found that, in the case of fracture of bolts in the package connecting the frame elements, the damage of the bolts is the result of the fretting corrosion due to the mutual friction between bolts and elements of skin, belt, and tape. Fretting corrosion develops in the locations of the cadmium coating damage of bolts in the process of friction. The break-in scuffing of the openings and corrosive damage (fretting corrosion) triggering intergranular fracture, which is the most severe in the skin and tape, contribute to the fractures in the belt, skin, and tape. The reason for fracture is structural and technological factors: high stresses in the investigated package, micro-displacement of the mating parts, violation of the cadmium coating, insufficient protection against corrosion and environmental impact. Fracture of the self-locking nuts made of 30KhGSA steel with the anticorrosion cadmium coating used during assembly of an auxiliary gas turbine engine is induced by their severe overheating—the impact of the melted coating on the surface of the loaded nuts and penetration of the liquid metal into the base material along the grain boundaries. Application of the cadmium coating for the operation of the steel parts at a temperature exceeding (even for a short time) the melting temperature of Cd (Tmelt = 320.9°C) under the condition of contact with the stressed metal owing to the Rebinder effect leads to a dramatic loss of strength and premature failure of the part. Fracture of the galvanized bolts made of 30KhGSA steel was studied in the process of the repeated static testing. It was found that several factors contributed to the onset of the multiple fractures: rough scratch marks, sandblasting performed before galvanizing with the use of large sand fractions, dents which contribute to the premature origin of cracks, areas with deposits formed during coating with loose adhesion of the layer. The presence of a large number of pits along with the fatigue grooves indicates the operation of the material under high load. The investigation was carried out by the method of optical and scanning electron microscopy applying the X-ray microanalysis.

Inorganic Materials. 2019;55(15):1481-1489
pages 1481-1489 views

Friction and Wear of Al2O3 + G Nanocomposite Produced via Spark Plasma Sintering

Stolyarov V.V., Klyatskina E.A.

Abstract

We report the effect of graphene (G) allotropic carbon modification in a content range of 0.5–2.0 wt % on the tribological, strength, and structural characteristics of an Al2O3/G nanocomposite produced by a 10-min plasma spark sintering (at a pressure of 50 MPa and a temperature of 1550°C) of a nanopowder mixture, previously subjected to ultrasonic dispersion in organic solvent. Its lubricant free friction and wear are tested at room temperature on a tribometer under a load of 20 N, at a roundabout motion of a ruby ball penetrator on a disk. The nanohardness and elastic modulus of the nanocomposite are determined via kinetic indentation. The fracture surface structure and friction track are monitored using a scanning electron microscope. The microstructure in the bulk of the nanocomposite was probed via dark- and bright-field transmission electron microscopy scanning of thin foils. The thermal stability of graphene was monitored via Raman spectroscopy. The introduction of graphene is shown to improve micro- and nanohardness, elasticity, and wear resistance by two to three orders of magnitude, as well as to slightly decrease the coefficient of friction. A graphene content of 2 wt % alters the mechanism of wear from brittle fracture to viscous shear owing to stronger coupling of matrix grains and the presence of agglomerates. A lack of degradation and the retention of graphene thermal stability are evidenced as well. The morphology of graphene particles reveals their preferential arrangement inside the corundum grains rather than at the grain boundaries.

Inorganic Materials. 2019;55(15):1490-1495
pages 1490-1495 views

Analysis of Propagation of Fatigue Cracks in Crane Girders

Moskvichev V.V., Chaban E.A.

Abstract

The results of analysis results of residual life of crane girders with operational defects based on numerical studies of the stress-strain state, the equations of limiting states, and the kinetic dependences of fatigue crack propagation formulated under criteria of strain and fracture mechanics are presented. A high level of wear of the fixed capital assets of engineering structures and metal constructions, as well as operation of the facilities in beyond-design-basis terms, contributes to origination of emergencies caused by damage accumulation. Crane girders operated under emergency conditions caused by the presence of fatigue cracks of different length in the most dangerous zones of the girder wall with an eccentric application of crane load are studied. According to the results of a numerical experiment, the lines of stress intensity influence at the crack tips appearing at the upper zone of the wall when different values of loading eccentricity caused by the rail displacement from the vertical axis of girder cross section were revealed. The dependence of the fatigue crack length and of the stress intensity at the crack tip on the number of load cycles of the girder is determined. To evaluating the bearing capacity of crane girders operated in emergency conditions, it is proposed to use the effective values of the stress intensity factors calculated for specific loading conditions, taking into account the structural features of the girders, the sizes of emerging fatigue cracks, and their locations in the crane girders. According to the results of analysis, the diagrams making it possible to predict the remaining residual life of crane girders with a crack are constructed. On the basis of traditional design procedures of structures for cyclic crack resistance, the calculation algorithm for individual life of crane girders which includes the obligatory analysis of the stress-strain state of the crane girder with a crack at the upper zone of the wall is formulated and implemented.

Inorganic Materials. 2019;55(15):1496-1502
pages 1496-1502 views

Evaluating the Static Cracking Resistance of Thin-Walled Pressure Vessels

Aniskovich E.V., Lepihin A.M., Moskvichev V.V.

Abstract

The failure criteria and limit states for thin-walled pressure vessels are analyzed taking into account the influence of plastic deformations. The introduction describes the main problems in operation of thin-walled vessels working under internal excess pressure associated with technological defectiveness and reduction of the residual life. Typical technological and operational defects in welded joints of vessels and statistical data on their number and types are presented. The share of welding defects is 62% of the total number of defects, and the share of remaining types of defects is significantly less. Histograms of the dimensions of welding defects are drawn, and the distribution laws are determined: the length of undercuts is described by a lognormal distribution law, whereas the depth of undercuts is described by a normal distribution law. Further, the limiting states and fracture criteria of vessels with defects and cracks under the conditions of elastoplastic deformation of material are indicated. The advantages of using the generalized equations of the form of J-curves are shown for calculation of the cracking resistance. A formula is given for calculating the J-curves that associate the dimensionless J-integral with the dimensionless load. The stress-strain state of a thin-walled vessel with a surface half-elliptical crack and an internal elliptical crack is analyzed in a volumetric setting. The peculiarities of the stress and strain fields in the local region of the crack zone under elastoplastic deformation are investigated. For the vessel model with a surface half-elliptical crack and an internal elliptical crack under elastoplastic deformation, the energy criterion of fracture mechanics, the J-integral, is calculated, and the results of calculations are presented. The results are presented in the form of graphs of the dimensionless J-integral versus the geometrical dimensions of the vessel and crack. The equations of J-curves are obtained and the limit load for thin-walled vessels is determined which depends on geometrical dimensions, loading parameters, strength properties of the material, and characteristics of cracking resistance and deformation. From the J-curves and the deformation curve, a formula is derived for determining the dependence of the limit load on the crack size, loading parameters, and characteristics of the material. Using this formula, the dependences of the limiting pressure of the vessel under elastoplastic deformations on the ratio of crack length a to vessel wall thickness S (a/S) is plotted for surface and internal cracks with different ratios R/S (R is the shell radius) and Jc which allow estimating the limiting pressure levels of the safe operation of thin-walled vessels.

Inorganic Materials. 2019;55(15):1503-1510
pages 1503-1510 views

Acoustic Emission Analysis of Deformation and Damage Processes

Makhutov N.A.

Abstract

The change in acoustic emission parameters is observed upon a single static loading of a flat metal specimen coated with a brittle strain-sensitive coating. The acoustic emission signal activity (energy, number, and frequency) was recorded as the tensile loading time increased. The dislocation mechanism of deformation in the area of small elastic and elastoplastic deformations, being commensurate with yield stress deformations at further loading to the ultimate strength, is shown to be induced by the processes that occur at the nano- and micro-levels with the appropriate acoustic emission signal frequencies. On the other hand, the evolution of local deformations with the emergence of defects at the micro- and mesoscales should be accompanied by different signal structures with higher amplitudes and lower frequencies. This is likely due to the formation of mesocracks at the grain boundaries and dislocation cluster rich zones. In this case, the number of high energy signals is expected to decrease at simultaneously decreasing acoustic frequencies. When tensile tests are performed on relatively coarse grained steels of high strength and low ductility, the sound effects can be heard even by the human ear. In addition to the traditional analysis of these parameters, the acoustic emission spectra have been plotted for specified loading intervals. Using new integral parameters of those spectra, the general regularities of spectral changes from the region of higher to lower frequencies are shown with increasing number of signals. This fact indicates the oncoming of hazardous damaged states caused by stress propagation through a coated aluminum sample. The generalized parameters of spectral changes are given as well. This allows the indicated elastic and elastoplastic deformation features to be characterized by means of spectral tools and new integral diagnostic parameters.

Inorganic Materials. 2019;55(15):1511-1515
pages 1511-1515 views

Experimental and Numerical Sizing of Delamination Defects in Layered Composite Materials

Urnev A.S., Chernyatin A.S., Matvienko Y.G., Razumovskii I.

Abstract

A methodical approach to the estimation of the localization zone and geometric parameters of delamination defects in layered composite materials is discussed. It is based on mathematical processing of the experimental results of deformation measurements obtained with a grid of fiber-optic sensors. The results of methodological developments related to the determination of the optimal topology of the grid of sensors are shown to ensure the detection of defects of a given size with the necessary accuracy and determination of their parameters. Methods for computational analysis and simulation of the strain-stress state in the defect zone based on the algorithm used for modeling the problems of strain-stress analysis in the defect zone using 2D finite elements instead of 3D ones are reported. These procedures allow one to use models of lower dimensionality while retaining all the features of the strain-stress state. The results of methodological developments related to the determination of the defect parameters from the results of strain measurements using the methodology of solving the inverse problem are shown. This methodology is based on solving the problem of minimizing the discrepancy between the vector of deformation response and the vector of initial parameters. The technique is implemented as software consisting of a series of macros for ANSYS and programs for MATLAB. The results of cyclic testing of a sample made of a multilayer composite material with a delamination type of defects are presented. The increment in the defect size upon loading is estimated by the mathematical processing of data recorded by fiber-optic strain sensors glued on one of the sample surfaces based on the solution of the inverse problem. Comparison of the results of calculations of geometric parameters of the defects with the measurement data obtained by the method of ultrasonic flaw detection shows good agreement between them.

Inorganic Materials. 2019;55(15):1516-1522
pages 1516-1522 views

Study of the Effect of Strain Amplitude Ratio at Two-Frequency Cyclic Loading

Gadenin M.M.

Abstract

The operating modes of loading elements of machines and structures exhibit, as a rule, more complicated character of their loading cycles compared to sinusoidal used in the practice of calculations and experiments. It is noted that, in a number of cases, the actual conditions of load changing can be idealized by dual-frequency loading modes with superposition of the high-frequency component of the main workload attributed to the effects of vibrations, aero- and hydrodynamic impacts, regulation of the working process, etc. Testing of three steel samples with different cyclic properties has shown that such two-frequency regimes lead to a decrease in the durability in comparison with single-frequency loading equal in the amplitude of maximum stresses. This reduction depends on the parameters of the basic low-frequency and imposed high-frequency loads. Evaluation of this reduction can be performed both using the laws of summation of the damage expressed in the strain terms and using an analytical expression considered below, which includes the calculated or experimentally determined durability for single-frequency loading with the maximum (total) amplitude of the effective stress and the durability coefficient characteristic of each type of material and determined by the ratio of amplitudes and hours of low and high stresses. A computational-experimental analysis of the effect of the amplitude of low-frequency and superimposed high-frequency loading under two-frequency modes of stress change on the cyclic durability has shown that the imposition of the high-frequency component of cyclic deformation on the main low-cycle loading process leads to a significant decrease in the cyclic durability; the level of the decrease correlates with the level of ratios of amplitudes and frequencies of the summarized harmonic processes of load application.

Inorganic Materials. 2019;55(15):1523-1532
pages 1523-1532 views

Methodology of Studying Mechanical Properties of Reinforced Concrete

Eryshev V.A.

Abstract

In this paper, we study the mechanical properties of a complex composite material formed by steel and hardened concrete. A methodology of operative quality control of new credible concrete and reinforcement under both laboratory and field conditions, including determination of the strength and strain characteristics of materials, as well as cohesion forces determining their joint operation under load, is developed. A design of a mobile unit in which by means of reversal it is possible to change the load direction and to test the reinforced element of the established form under both tension and compression is presented. This reduces the nomenclature of test equipment and the number of forms for the manufacture of concrete samples. The values ​​of intrinsic stresses and the magnitude of deformations due to concrete shrinkage are determined by the forces of the crack formation in concrete when the joint operation of concrete and reinforcement is broken. An analytical dependence of the forces and deformations of a reinforced concrete sample with central reinforcement upon axial tension and compression taking into account deformations and stresses in the reinforcement and concrete on the concrete shrinkage is established. The results of experimental studies including concrete tensile diagrams and diagrams of the development of axial deformations with increasing load under central loading of reinforced elements are presented. A methodology of accounting for account stresses and strains due to concrete shrinkage in calculations of reinforced concrete structures is developed. The effectiveness of analytical expressions that establish a relationship between stresses and strains in material diagrams for calculations of reinforced concrete structures using a deformation model is estimated.

Inorganic Materials. 2019;55(15):1533-1538
pages 1533-1538 views

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