Synthesis and characterization of the MIIU3O10 · 6H2O (MII = Ni, Zn) triuranates


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We have developed a process for the synthesis of Ni(II) and Zn(II) triuranates with the general formula MIIU3O10 · 6H2O through reaction of schoepite, UO3 · 2.25H2O, with aqueous solutions of nickel and zinc nitrates under hydrothermal conditions. Using chemical analysis, X-ray diffraction, IR spectroscopy, and thermal analysis, we have determined the composition and structure of the triuranates and investigated their dehydration and thermal decomposition.

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O. Nipruk

Lobachevsky State University

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Email: nipruk@yandex.ru
俄罗斯联邦, pr. Gagarina 23, Nizhny Novgorod, 603950

N. Chernorukov

Lobachevsky State University

Email: nipruk@yandex.ru
俄罗斯联邦, pr. Gagarina 23, Nizhny Novgorod, 603950

K. Chaplieva

Lobachevsky State University

Email: nipruk@yandex.ru
俄罗斯联邦, pr. Gagarina 23, Nizhny Novgorod, 603950

G. Chernorukov

Lobachevsky State University

Email: nipruk@yandex.ru
俄罗斯联邦, pr. Gagarina 23, Nizhny Novgorod, 603950

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