Synthesis and characterization of the MIIU3O10 · 6H2O (MII = Ni, Zn) triuranates


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Abstract

We have developed a process for the synthesis of Ni(II) and Zn(II) triuranates with the general formula MIIU3O10 · 6H2O through reaction of schoepite, UO3 · 2.25H2O, with aqueous solutions of nickel and zinc nitrates under hydrothermal conditions. Using chemical analysis, X-ray diffraction, IR spectroscopy, and thermal analysis, we have determined the composition and structure of the triuranates and investigated their dehydration and thermal decomposition.

About the authors

O. V. Nipruk

Lobachevsky State University

Author for correspondence.
Email: nipruk@yandex.ru
Russian Federation, pr. Gagarina 23, Nizhny Novgorod, 603950

N. G. Chernorukov

Lobachevsky State University

Email: nipruk@yandex.ru
Russian Federation, pr. Gagarina 23, Nizhny Novgorod, 603950

K. A. Chaplieva

Lobachevsky State University

Email: nipruk@yandex.ru
Russian Federation, pr. Gagarina 23, Nizhny Novgorod, 603950

G. N. Chernorukov

Lobachevsky State University

Email: nipruk@yandex.ru
Russian Federation, pr. Gagarina 23, Nizhny Novgorod, 603950

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