Synthesis and characterization of the MIIU3O10 · 6H2O (MII = Ni, Zn) triuranates
- Authors: Nipruk O.V.1, Chernorukov N.G.1, Chaplieva K.A.1, Chernorukov G.N.1
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Affiliations:
- Lobachevsky State University
- Issue: Vol 52, No 5 (2016)
- Pages: 504-509
- Section: Article
- URL: https://journals.rcsi.science/0020-1685/article/view/157584
- DOI: https://doi.org/10.1134/S0020168516050113
- ID: 157584
Cite item
Abstract
We have developed a process for the synthesis of Ni(II) and Zn(II) triuranates with the general formula MIIU3O10 · 6H2O through reaction of schoepite, UO3 · 2.25H2O, with aqueous solutions of nickel and zinc nitrates under hydrothermal conditions. Using chemical analysis, X-ray diffraction, IR spectroscopy, and thermal analysis, we have determined the composition and structure of the triuranates and investigated their dehydration and thermal decomposition.
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About the authors
O. V. Nipruk
Lobachevsky State University
Author for correspondence.
Email: nipruk@yandex.ru
Russian Federation, pr. Gagarina 23, Nizhny Novgorod, 603950
N. G. Chernorukov
Lobachevsky State University
Email: nipruk@yandex.ru
Russian Federation, pr. Gagarina 23, Nizhny Novgorod, 603950
K. A. Chaplieva
Lobachevsky State University
Email: nipruk@yandex.ru
Russian Federation, pr. Gagarina 23, Nizhny Novgorod, 603950
G. N. Chernorukov
Lobachevsky State University
Email: nipruk@yandex.ru
Russian Federation, pr. Gagarina 23, Nizhny Novgorod, 603950
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