Structural and Optoelectron Properties of Hybrid Perovskite Crystals


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Abstract

The structure and photoluminescence of CH3NH3PbI3 (lead triiodide methylammonium) synthesized perovskite crystals are investigated in a wide temperature range. As temperature rises to 130–140 K, there is a junction from an orthorhombic to tetragonal crystal lattice with a change in the bandwidth. An increase in the stationary photoluminescence intensity at room temperature under the influence of exciting emission is revealed. A model explaining the observed growth of photoluminescence is proposed.

About the authors

O. I. Semenova

Rzhanov Institute of Semiconductor Physics, Siberian Branch

Author for correspondence.
Email: oisem@isp.nsc.ru
Russian Federation, pr. Akademika Lavrentyeva 13, Novosibirsk, 630090

D. S. Abramkin

Rzhanov Institute of Semiconductor Physics, Siberian Branch

Email: oisem@isp.nsc.ru
Russian Federation, pr. Akademika Lavrentyeva 13, Novosibirsk, 630090

I. A. Derebezov

Rzhanov Institute of Semiconductor Physics, Siberian Branch

Email: oisem@isp.nsc.ru
Russian Federation, pr. Akademika Lavrentyeva 13, Novosibirsk, 630090

A. N. Shmakov

Boreskov Institute of Catalysis, Siberian Branch

Email: oisem@isp.nsc.ru
Russian Federation, pr. Akademika Lavrentyeva 5, Novosibirsk, 630090

A. V. Gaisler

Rzhanov Institute of Semiconductor Physics, Siberian Branch

Email: oisem@isp.nsc.ru
Russian Federation, pr. Akademika Lavrentyeva 13, Novosibirsk, 630090

V. A. Gaisler

Rzhanov Institute of Semiconductor Physics, Siberian Branch

Email: oisem@isp.nsc.ru
Russian Federation, pr. Akademika Lavrentyeva 13, Novosibirsk, 630090

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