INFLUENCE OF INTRAMOLECULAR DONOR-ACCEPTOR INTERACTIONS ON RADIOLYSIS OF ORGANIC COMPOUNDS: EFFECTS IN ACETYLACETONE

S. I. Vlasov; Власов С. И.; A. V. Ponomarev; Пономарев А. В.; B. G. Ershov; Ершов Б. Г.

doi:10.31857/S2686953523600174

INFLUENCE OF INTRAMOLECULAR DONOR-ACCEPTOR INTERACTIONS ON RADIOLYSIS OF ORGANIC COMPOUNDS: EFFECTS IN ACETYLACETONE

Авторлар: Vlasov S.¹, Ponomarev A.¹, Ershov B.¹
Мекемелер:
1. A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Шығарылым: Том 510, № 1 (2023)
Беттер: 69-73
Бөлім: ФИЗИЧЕСКАЯ ХИМИЯ
URL: https://journals.rcsi.science/2686-9535/article/view/135979
DOI: https://doi.org/10.31857/S2686953523600174
EDN: https://elibrary.ru/YRXCAM
ID: 135979

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Аннотация
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Әдебиет тізімі
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Статистика

Аннотация

Using acetylacetone as an example, it was shown that the intramolecular hydrogen bond significantly affects the radiolytic transformations of organic compounds, suppressing the transfer of a proton from the primary radical cation to the molecule, and also contributing to the cleavage of the C–OH bond in the enol form. Due to these effects, the main heavy product of radiolysis at 295 K is 4-oxopent-2-en-2-yl acetate. Under boiling conditions (413 K), hydrogen bonds are eliminated, leading to the predominant formation of 4-hydroxy-2-pentanone, which is not detected at 295 K.

Негізгі сөздер

acetylacetone, tautomers, hydrogen bond, radiolysis, proton transfer, radical recombination

Әдебиет тізімі

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