UNEXPECTED SELECTIVE REDUCTION OF 3- AND 6-HALOGENQUINOLINES AND 2‑BROMO-1-METHYLBENZIMIDAZOLE WITH RED PHOSPHORUS IN THE KOH/DMSO SYSTEM

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详细

3-Bromo- and 6-chloroquinolines or 2-bromo-1-methylbenzimidazole react with red phosphorus in the KOH/DMSO (Н2О) system upon heating (100–120°C, 3 h), forming selective reduction products in high yield (with preservation of the aromatic heterocycle), forming quinoline and 1-methylbenzimidazole, correspondingly.

作者简介

V. Kuimov

Favorsky Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: boris_trofimov@irioch.irk.ru
Russian, 664033, Irkutsk

S. Malysheva

Favorsky Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: boris_trofimov@irioch.irk.ru
Russian, 664033, Irkutsk

N. Belogorlova

Favorsky Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: boris_trofimov@irioch.irk.ru
Russian, 664033, Irkutsk

B. Trofimov

Favorsky Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

编辑信件的主要联系方式.
Email: boris_trofimov@irioch.irk.ru
Russian, 664033, Irkutsk

参考

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版权所有 © В.А. Куимов, С.Ф. Малышева, Н.А. Белогорлова, Б.А. Трофимов, 2023

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