Inversion of surface conductivity type in correlated topological insulator SmB6

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Abstract

The potential to control the type of surface conductivity in the correlated topological insulator SmB6 was demonstrated for the first time. The transition to p-type surface conductivity with the Hall effect sign inversion at helium temperatures was achieved by cleaning the SmB6 faces formed by the (110) surfaces with the help of argon ion sputtering with an average energy of 500 eV. The crossover in the surface conductivity type with a dominant contribution from surface holes (having mobility up to 60 cm2V−1s−1 at 2 K) is associated with both the removal of carbon from the surface of SmB6 and its passivation by oxygen, and with the generation of defects in the near-surface layer initiated by ion bombardment. The discovered effect opens up possibilities for modifying the parameters of surface electron transport in the correlated topological insulator SmB6 by means of the controlled injection of defects or due to the field effect.

About the authors

V. V Glushkov

Prokhorov General Physics Institute of the Russian Academy of Sciences

Email: glushkov@lt.gpi.ru
Moscow, Russian Federation

A. D Bozhko

Prokhorov General Physics Institute of the Russian Academy of Sciences

Email: glushkov@lt.gpi.ru
Moscow, Russian Federation

V. S Zhurkin

Prokhorov General Physics Institute of the Russian Academy of Sciences

Email: glushkov@lt.gpi.ru
Moscow, Russian Federation

V. M Shevlyuga

Prokhorov General Physics Institute of the Russian Academy of Sciences

Email: glushkov@lt.gpi.ru
Moscow, Russian Federation

B. V Andryushechkin

Prokhorov General Physics Institute of the Russian Academy of Sciences

Author for correspondence.
Email: glushkov@lt.gpi.ru
Moscow, Russian Federation

References

  1. Kikoin K.A., Mishchenko A.S. Magnetic excitations in intermediate-valence semiconductors with a singlet ground state // J. Phys. Condens. Matter. 1995. V. 7. No 2. P. 307–314. https://doi.org/10.1088/0953-8984/7/2/008
  2. Sluchanko N.E., Glushkov V.V., Gorshunov B.P, Demishev S.V., Kondrin M.V., Pronin A.A., Volkov A.A., Savchenko A.K., Grűner G., Bruynseraede Y, Moshchalkov V.V., Kunii S. Intragap states in SmB6 // Phys. Rev. B. 2000. V. 61. No 15. P. 9906–9909. https://doi.org/10.1103/PhysRevB.61.9906
  3. Akintola K., Pal A., Dunsiger S.R., Fang A.C.Y., Potma M., Saha Sh.R., Wang X., Paglione J., Sonier J.E. Freezing out of a low-energy bulk spin exciton in SmB6 // Quantum Materials. 2018. V. 3. I. 1. P. 36–1–6. https://doi.org/10.1038/s41535-018-0110-7
  4. Zyuzin V.A. JETP Letters, 120 (10), р. 766–771 (2024).
  5. Neupane M., Alidoust N., Xu S-Y., Kondo T., Ishida Y., Kim D.J., Liu Ch., Belopolski I., Jo Y.J., Chang T-R., Jeng H-T., Durakiewicz T., Balicas L., Lin H., Bansil A., Shin S., Fisk Z., Hasan M.Z. Surface electronic structure of the topological Kondo-insulator candidate correlated electron system SmB6 // Nat. Commun. 2013. V. 4. No 1. P. 2991–1–7. https://doi.org/10.1038/ncomms3991
  6. Li L., Sun K., Kurdak C., Allen J.W. Emergent mystery in the Kondo insulator samarium hexaboride // Nat. Rev. Phys. 2020. V. 2. I. 9. P. 463–479. https://doi.org/10.1038/s42254-020-0210-8
  7. Demishev S.V., Anisimov M.A., Voronov V.V., Gilmanov M.I., Glushkov V.V., Karasev M.S., Filipov V.B., and Shitsevalova N.Yu. Doklady Physics, 65 (7), р. 9–13 (2020).
  8. Suga S., Sakamoto K., Okuda T., Miyamoto K., Kenta K., Sekiyama A., Yamaguchi J., Fujiwara H., Irizawa A., Ito T., Kimura Sh., Balashov T., Wulfhekel W., Yeo S., Iga F., Imada S. Spin-Polarized Angle-Resolved Photoelectron Spectroscopy of the So-Predicted Kondo Topological Insulator SmB6 // J. Phys. Soc. Japan. 2014. V. 83. No 1. P. 014705–1–6. https://doi.org/10.7566/JPSJ.83.014705
  9. Hlawenka P., Siemensmeyer K., Weschke E., Varykhalov A., Sánchez-Barriga J., Shitsevalova N.Y., Dukhnenko A.V., Filipov V.B., Gabáni S., Flachbart K., Rader O., Rienks E.D.L. Samarium hexaboride is a trivial surface conductor // Nat. Comm. 2018. V. 9. No 1. P. 517–1–7. https://doi.org/10.1038/s41467-018-02908-7
  10. Zonno M., Michiardi M., Boschini F., Levy G., Volckaert K., Curcio D., Bianchi M., Rosa P.F.S., Fisk Z., Hofmann Ph., Elfimov I.S., Green R.J., Sawatzky G.A., Damascelli A. Mixed-valence state in the dilute-impurity regime of La-substituted SmB6 // Nat. Comm. 2024. V. 15. I. 1. P. 7621–1–7. https://doi.org/10.1038/s41467-024-51569-2
  11. Herrmann H., Hlawenka P., Siemensmeyer K., Weschke E., Sánchez-Barriga J., Varykhalov A., Shitsevalova N.Y., Dukhnenko A.V., Filipov V.B., Gabáni S., Flachbart K., Rader O., Sterrer M., Rienks E.D.L. Contrast Reversal in Scanning Tunneling Microscopy and Its Implications for the Topological Classification of SmB6 // Adv. Mater. 2020. V. 32. I. 10. P. 1906725–1–5. https://doi.org/10.1002/adma.201906725
  12. Matt С.E., Pirie H., Soumyanarayanan A., Yang H., Yee M.M., Chen P., Yu L., Larson D.T., Paz W.S., Palacios J.J., Hamidian M.H., Hoffman J.E. Consistency between ARPES and STM measurements on SmB6 // Phys. Rev. B. 2020. V. 101. I. 8. P. 085142–1–7. https://doi.org/10.1103/PhysRevB.101.085142
  13. Wirth S., Schlottmann P. An STM Perspective on Hexaborides: Surface States of the Kondo Insulator SmB6 // Adv. Quantum Technol. 2021. V. 4. I. 12. P. 2100102–1–21. https://doi.org/10.1002/qute.202100102
  14. Kim D.J., Thomas S., Grant T., Botimer J., Fisk Z., Xia J. Surface Hall effect and nonlocal transport in SmB6: Еvidence for surface conduction // Sci. Rep. 2013. V. 3. I. 1. P. 3150–1–4. https://doi.org/10.1038/srep03150
  15. Crivillero M.V.A., König M., Souza J.C., Pagliuso P.G., Sichelschmidt J., Rosa P.F.S., Fisk Z., Wirth S. Systematic manipulation of the surface conductivity of SmB6 // Phys. Rev. Res. 2021. V. 3 I. 2. P. 023162–1–7. https://doi.org/10.1103/PhysRevResearch.3.023162
  16. Eo Y.S., Rakoski A., Sinha S., Mihaliov D., Fuhrman W.T., Saha S.R., Rosa P.F.S., Fisk Z., Hatnean M.C., Balakrishnan G., Chamorro J.R., Phelan W.A., Koohpayeh S.M., McQueen T.M., Kang B., Song M., Cho B., Fuhrer M.S., Paglione J., Kurdak Ç. Bulk transport paths through defects in floating zone and Al flux grown SmB6 // Phys. Rev. Mater. 2021. V. 5. I. 5. P. 055001–1–9. https://doi.org/10.1103/PhysRevMaterials.5.055001
  17. Syers P., Kim D., Fuhrer M. S., Paglione J. Tuning Bulk and Surface Conduction in the Proposed Topological Kondo Insulator SmB6 // Phys. Rev Lett. 2015. V. 114. I. 9. P. 096601–1–5. https://doi.org/10.1103/PhysRevLett.114.096601
  18. Kong D., Chen Y., Cha J.J., Zhang Q., Analytis J.G., Lai K., Liu Z., Hong S.S., Koski K.J., Mo S.-K., Hussain Z., Fisher I.R., Shen Z.-X., Cui Y. Ambipolar field effect in the ternary topological insulator (BixSb1–x)2Te3 by composition tuning // Nat. Nanotech. 2011. V. 6. I. 11. P. 705–709. https://doi.org/10.1038/nnano.2011.172
  19. Glushkov V.V., Zhurkin V.S., Bozhko A.D., Kudryavtsev O.E., Andryushechkin B.V., Komarov N.S., Voronov V.V., Shitsevalova N.Yu., and Filipov V.B. JETP Letters, 116 (11), р. 791–797 (2022).
  20. Shitsevalova N.Yu. Crystal chemistry and crystal growth of rare-earth borides / In: D. S. Inosov (Ed.), Rare-Earth Borides. N.Y.: Jenny Stanford Publishing, 2021. Ch. 1. P. 1–238.
  21. Kovalenko S.L., Pavlova T.V., Andryushechkin B.V., and Eltsov K.N. JETP Letters, 111 (10), р. 591–597 (2020).
  22. Madden H.H. J. Vac. Sci. Technol., 18 (3), р. 677–689 (1981).
  23. Joyner D.J., Hercules D.M. Chemical bonding and electronic structure of B2O3, H3BO3, and BN: An ESCA, Auger, SIMS, and SXS study // J. Chem. Phys. 1980. V. 72. I. 2. P. 1095–1108. https://doi.org/10.1063/1.439251
  24. Sittler J.A., Park W.K. Self-oxidation-formed boron oxide as a tunnel barrier in SmB6 junctions // J. All. Comp. 2021. V. 874. P. 159841–1–8. https://doi.org/10.1016/j.jallcom.2021.159841
  25. Zabolotnyy V.B., Fürsich K., Green R.J., Lutz P., Treiber K., Min C.-H., Dukhnenko A.V., Shitsevalova N.Y., Filipov V.B., Kang B.Y., Cho B.K., Sutarto R., He F., Reinert F., Inosov D.S., Hinkov V. Chemical and valence reconstruction at the surface of SmB6 revealed by means of resonant soft x-ray reflectometry // Phys. Rev. B. 2018. V. 97. I. 20. P. 205416–1–12. https://doi.org/10.1103/PhysRevB.97.205416

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