Composites Based on Biodegradable Polymers and Layered Structures

A. V. Khlyustova; Хлюстова А. В.; A. V. Agafonov; Агафонов А. В.; V. A. Titov; Титов В. А.; A. V. Evdokimova; Евдокимова А. В.; V. D. Shibaeva; Шибаева В. Д.; A. S. Kraev; Краев А. С.; N. A. Sirotkin; Сироткин Н. А.

doi:10.31857/S2308113923600016

Composites Based on Biodegradable Polymers and Layered Structures

Authors: Khlyustova A.V.¹, Agafonov A.V.¹, Titov V.A.¹, Evdokimova A.V.¹, Shibaeva V.D.¹, Kraev A.S.¹, Sirotkin N.A.¹
Affiliations:
1. Krestov Institute of Solution Chemistry, Russian Academy of Sciences
Issue: Vol 65, No 5 (2023)
Pages: 384-391
Section: КОМПОЗИТЫ
URL: https://journals.rcsi.science/2308-1139/article/view/233629
DOI: https://doi.org/10.31857/S2308113923600016
EDN: https://elibrary.ru/CRKORV
ID: 233629

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Abstract

The paper presents the results of mechanical and electrical tests of composite materials based on biodegradable polymers (polyvinyl alcohol, polyacrylamide, starch) and synthetic layered double hydroxides (Ni–Al, Zn–Al) obtained by two-stage (chemical) and one-stage (plasma chemical) methods. The one-stage method for producing composites involves the formation of filler structures during the burning of low-temperature plasma in the bulk of an aqueous polymer solution. Electrode materials were used as precursors. Regardless of the production method, 2D hexagonal structures are formed and embedded in the polymer matrix. This is evidenced by IR spectroscopy data showing shifts in the main characteristic bands and the appearance of new ones. It has been established that layered fillers can be both plasticizers and reinforcing agents. The influence of the viscosity of the polymer matrix on the mechanical characteristics of the composites has been revealed. The introduction of fillers changes the surface roughness, leading to an increase in hydrophobicity of the composites. It has been established that the current–voltage curves of the composites are nonlinear, so that such composites can be considered as flexible analogues of nonlinear electronic components.

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